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  • 2005-2009  (5)
  • 2006  (5)
Material
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  • 2005-2009  (5)
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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 314 (July 2006), p. 13-18 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The electrical field drop over a deposit during electrophoretic deposition (EPD)determines the deposition rate and the uniformity of the deposit when a non-uniform electrical fieldis present. Due to the large practical consequences of a potential drop over the deposit, a procedurewas developed to calculate the electrical field strength at the deposition front from currentconductivitymeasurements during EPD. The evolution of the electrical field strength during EPDwas calculated for MEK and ethanol based suspensions. It was found that the suspensioncomposition determines whether a potential drop over the deposit is present or not. EPDexperiments on a membrane revealed that the extra potential drop is over the deposit and not causedby electrode polarization for the ethanol-acid based suspensions
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 314 (July 2006), p. 213-218 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Due to their excellent properties of high strength, biocompatibility and stability inphysiological environments, ceramics are investigated as bone substitute materials. In this wayceramic components have been used for total hip replacement components since the early 1970s.Alumina and zirconia monoliths are mainly used for these components. However, zirconia canundergo low temperature degradation in aqueous environment and alumina is brittle.To increase the strength, functionally graded Al2O3/ZrO2 ball-heads and acetabular cup inserts weremade in this work by electrophoretic deposition (EPD). A composition gradient in alumina andzirconia was engineered to obtain a pure alumina surface region and a homogeneousalumina/zirconia core with intermediate continuously graded regions to generate thermal residualstresses at the surface after sintering.Experimental work revealed that a sequence of counter-electrodes was necessary to EPD complexshaped functionally graded material (FGM) components. To obtain deposits with a shape differentfrom the deposition electrode, the deposit was grown up to the counter-electrode and the design ofthe counter-electrodes was supported by electrical field calculations to generate a constant electricfield at the surface of the deposition electrode
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 314 (July 2006), p. 181-186 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A model was developed to explain the magnitude of the potential drop over the depositfor non-conductive powders during electrophoretic deposition (EPD). The magnitude of thepotential drop over the deposit is explained in terms of a reduced ion transport through the deposit,as controlled by the pore potential that is related to the thickness of the electrostatic double layerrelative to the pore radius and the magnitude of the surface potential of the powder particles. Thismodel was validated for EPD of Al2O3 powder from ethanol-based suspensions with HNO3addition. The specific resistivity of the deposit could be related to the calculated potential in thepores of the deposit
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Advances in science and technology Vol. 45 (Oct. 2006), p. 1075-1084 
    ISSN: 1662-0356
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Natural Sciences in General , Technology
    Notes: Electrophoresis is the effect that when an electric field is applied to a suspension of apowder in a liquid, the powder particles move under influence of this field. Frequently the powderparticles also deposit at one of the electrodes. The form of the electrode determines the form of thedeposit, hence shaping is possible. The current insights into the science and technology ofelectrophoretic deposition (EPD) will be summarized. EPD is well suited for shaping layeredmicrostructures (laminates), by simply changing repeatedly between two or more suspensionsduring deposition. Tubular laminates consisting of silicon carbide layers and crack deflectinggraphite interlayers have been produced. These tubes demonstrate an enhanced fracture energy anda gradual mode of failure. Another area of advanced ceramics where the use of EPD makes senseare functionally graded materials (FGM) in which one tries to combine in one component highhardness and high toughness. EPD allows the formation of FGM by depositing from a powdersuspension to which a second suspension is continuously added during the process. An examplewill be shown of a graded WC-Co hardmetal
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 314 (July 2006), p. 187-194 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The deposit can induce an extra potential drop near the electrode, depending on thesuspension composition. This can result in a levelling off of the deposition rate in a constant-voltagedeposition process. The magnitude of the extra voltage drop determines the uniformity of thedeposit as function of the uniformity of the electric field present at the deposition electrode. It wasexperimentally proven that a uniform Al2O3 coating thickness was obtained in a non-homogeneouselectrical field in ethanol with addition of HNO3, while the coating thickness varied uniformly withthe E-field strength for a MEK with n-butylamine based suspension. The uniformity of the coatingdeposited from these suspensions was related to the measured potential drop over the deposit duringelectrophoretic deposition
    Type of Medium: Electronic Resource
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