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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 68 (1996), S. 2648-2650 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Irradiation of polytetrafluoroethylene films with vacuum UV light in an ammonia gas atmosphere resulted in a hydrophilic surface, where abstraction of fluorine atoms, and introduction of nitrogen, oxygen, and hydrogen atoms occurred. We used Kr2* and Xe2* excimer lamps at wavelength of 146 and 172 nm, respectively. The reaction mechanism for chemical surface modification is discussed on the basis of x-ray photoelectron spectroscopy, secondary ion mass spectroscopy, and attenuated total reflection Fourier transform infrared spectroscopy analyses. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 68 (1999), S. 515-523 
    ISSN: 1432-0630
    Keywords: PACS: 79.20.D; 61.41; 84.37
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. We present observations of sub-micron- to micron-sized particles generated by high fluence (≈2 J/cm2) 248-nm laser ablation of pressed polytetrafluorethylene (PTFE) targets in air at atmospheric pressure. The original target material was hydrostatically compressed ≈7 μm PTFE powder, sintered at 275 °C. Collected ejecta due to laser irradiation consists of four basic particle morphologies ranging from small particles 50–200 nm in diameter to larger particles ≈10 μm in diameter. Many particles formed in air carry electric charge. Using charged electrodes we are able to collect charged particles to determine relative numbers of ± charge. We observe roughly equal numbers of positively and negatively charged particles except for the largest particles which were predominantly negative. For a range of particle sizes we are able to measure the sign and magnitude of this charge with a Millikan-oil-drop technique and determine surface charge densities. The implications of these observations with respect to pulsed laser deposition of PTFE thin films and coatings are discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 69 (1999), S. S87 
    ISSN: 1432-0630
    Keywords: PACS: 47.40.-x; 52.50.Jm; 42.62.-b
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. A simplified model of plume expansion into ambient atmosphere is presented which is based on the laws of mass, momentum, and energy conservation. In the course of expansion, the energy is redistributed between the thermal and kinetic energies of the plume and (internal and external) shock waves (SW). The expansion is described by ordinary differential equations for the characteristic radii (contact surface, position of the SWs). The initial stage is similar to inertial expansion into vacuum, with radius R∝t. Internal SW propagates inwards from the contact surface. Later expansion follows a point-blast model with R∝t2/5. Here the homogenized plume is decelerated and heated because of the counter-pressure of the ambient gas, which forms external SW. At a certain distance from the target, the plume stops (and even contracts), while external SW weakens and detaches from the contact surface. Analytical formulas for the transitional stages of expansion are discussed, and theoretical predictions are compared with experimental results of laser ablation of steel and YBCO in Ar.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-0630
    Keywords: PACS: 42.62; 61.80; 68.35
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. Single-pulse excimer-laser irradiation of poly-ethylene-terephthalate (PET) with fluences around and above the ablation threshold leads to the formation of surface dendrites. The lateral size and the number density of dendrites depend on the laser wavelength and the type and pressure of the ambient atmosphere. The results are discussed on the basis of excimer-laser-induced polymer fragmentation and the redeposition of ablation products.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 69 (1999), S. S467 
    ISSN: 1432-0630
    Keywords: PACS: 79.20.Ds; 61.41.+e; 84.37.+i
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. KrF-laser ablation of pressed polytetrafluoroethylene (PTFE) targets is accompanied by the ejection of submicron- to micron-sized particles. Collected ejecta consist of four basic particle morphologies ranging from small particles 50–200 nm in diameter to larger particles ∼10 μm in diameter. Many particles carry electric charge as measured by using charged electrodes and by the Millikan technique. Thin PTFE films deposited by pulsed laser deposition (PLD) from the same targets onto heated Si substrates are highly crystalline and show only a minor but detectable increase of defects compared with the target material. The transferred particulates mainly consist of long PTFE molecule chains. The low molecular weight material that is also transferred to the substrate mainly either links with other low molecular weight material or evaporates during deposition.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 65 (1997), S. 259-261 
    ISSN: 1432-0630
    Keywords: PACS: 42.55G; 68.35; 81.40; 82.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: 3 N4 has been investigated. The ablation threshold in air, Φth, is around 0.3±0.1 J/cm2 with ArF- and 0.9±0.2 J/cm2 with KrF-laser radiation. With fluences Φth〈Φ〈4 J/cm2 the irradiated surface is either very flat or it exhibits a cone-type structure, depending on the number of laser pulses employed. With fluences of 5 to 10 J/cm2, the sample surface becomes very smooth, much smoother than the original mechanically polished surface. Pores, scratches, and cracks observed on the non-irradiated surface are absent within the illuminated area. In this regime, the ablation rates are typically 0.1 to 0.2 μm/pulse.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 567-568 (Dec. 2007), p. 257-260 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This work is focused on laser modification of polymers with different angles ofincidence. Periodic surface structures generated by linearly polarized F2 laser light (157 nm) onpolyethyleneterephthalate (PET) were studied. Atomic force microscopy was used to study thetopological changes induced by the laser irradiation. The laser irradiation induces the formation ofperiodic ripple structures, the width of and the height being angle dependent. The periodic structureswere formed with the laser fluence 4.70 mJ/cm2. The laser modified PET foils were coated with a50 nm thick gold layer by sputtering. After Au deposition on the laser PET foils with ripplestructure, the roughness of surface decreases in comparison to PET with ripples without Au coating
    Type of Medium: Electronic Resource
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