ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Attenuated total reflectance (ATR) FTIR spectroscopy was utilized for surface studies of ammonia/plasma-modified poly(dimethylsiloxane) (PDMS) elastomer networks containing residual chloro-functional molecules. Ammonia/plasma modification of PDMS containing chloro-functional molecules causes the formation of surface amide groups, but due to the parallel formation of surface ammonium chloride, amide groups are not chemically bonded to the PDMS surface. The two primary sources of chlorine-containing species are residual traces of freon and cross-linking initiators present in the network. In the absence of chloro-functional molecules, ammonia/plasma surface modifications of PDMS leads to the formation of stable surface amide groups.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1992.070440304
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