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  • 2005-2009  (1)
  • 1985-1989  (3)
  • 1960-1964  (3)
  • 1950-1954  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 56 (1985), S. 2038-2042 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The characteristics of a molecular beam from a piezoelectric pulsed nozzle source are given and, where appropriate, compared to a continuous beam. These include variation during the pulse in the relative intensity and speed ratio for the gases He, Ar, Ne, and N2. The measurements were made by standard time-of-flight and laser-induced fluorescence techniques. For gas valve pulses of time duration less than 500 μs, there was a single peak during which the gases reached continuum steady flow behavior. Typical speed ratios (parallel temperatures) for the gases He, Ar, Ne, and N2 were 19, 34, 34, and 20 (2.1, 0.7, 0.7, and 1.9 K), respectively. These values are comparable to those from a continuous source with equivalent values of p0d, the product of source pressure and nozzle diameter. The dimer concentrations for Ne and Ar were also measured and found to be 0.4% and 0.7%, respectively. A major problem with the valve was its inability to open fully because of the limited motion of the piezoelectric element.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2671-2683 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In a crossed molecular beams Ar–O2 time-of-flight scattering experiment individual rotational state-to-state transitions are observed up to values of Δj=18. For the collision energy Ec.m.=97 meV a maximum of excitation is found in the neighborhood of the 1→13 rotational transition. In the total differential cross section fast diffraction oscillations could experimentally be resolved. In addition, a new method is explored for extracting cross section information on specific rotational transitions from measurements of appropriate out-of-plane and in-plane total differential laboratory cross sections only. A preliminary comparison of the experiment with theory indicates a need for substantial corrections in the anisotropy of the most recent Ar–O2 potential by as much as 0.2 A(ring).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Munksgaard International Publishers
    Ecology of freshwater fish 14 (2005), S. 0 
    ISSN: 1600-0633
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract – Although homing behaviour has been observed in juvenile Atlantic salmon, brown trout and resident cutthroat trout, this behaviour has not been well studied in juvenile Pacific salmon. We examined the site fidelity and homing behaviour of juvenile coho salmon (Oncorhynchus kisutch) by marking and relocating them within an off-channel habitat. Over 80% of displaced fish returned to the area from which they were originally collected. The proportion of fish that returned to the original location did not vary significantly among three sampling dates. However, we found that this proportion decreased over time in a brackish lagoon when we statistically analysed the data reported by Day (1966). Our results suggest that juvenile coho salmon exhibit strong site fidelity and are able to return to their home ranges after displacement. These behaviours are likely to be important for the winter survival of juvenile coho salmon.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 138 (1953), S. 81-90 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Zusammenfassung Durch Fällung mit Kaliumhexacyanoferrat(II) oder Kaliumhexacyanokobaltat(III) ist es möglich, den störenden Einfluß 2wertiger Metall-Ionen auf die alkalimetrische Titration der ersten Stufe der Phosphorsäure auszuschalten. Die Bedeutung der Neutralität der Fällungslösungen wird diskutiert. Nach Aufzeigen verschiedener Störungen und Fehlerquellen werden genaue Arbeitsanweisungen gegeben. Für die Beseitigung der durch 3 wertige Kationen verursachten Störungen wurde ein allgemein gangbarer Weg nicht gefunden. Komplexbildung führte nur in Spezialfällen, Ionenaustausch in keinem Fall zum Erfolg.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 37 (1986), S. 110-110 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 197 (1963), S. 217-221 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary The selective determination of metallic iron beside iron oxides may be carried out in a simple and rather accurate manner by treating the analysing sample with a solution of bromine in methanol. By this method, only the metallic iron is dissolved which, after filtering the oxides remained unsolved, may be determined by one of the known titrimetrical or photometrical procedures. The ferro-iron content of the oxide residue may appropriately be determined by the Vanadate titration method according to Wilson. Although a reaction with elementary chlorine at about 400°C quantitatively converts the metallic iron into FeCl3, it also transforms one third of the iron amount present in the form of ferrous oxide into the same compound. Consequently, this method is not suited for a direct determination of the metallic iron content although it affords a useful control of the sum: metallic iron + ferro-iron as obtained by the first mentioned method.
    Notes: Zusammenfassung Die selektive Bestimmung von metallischem Eisen neben Eisenoxiden ist in einfacher und recht genauer Weise durch Behandeln der Analysenprobe mit einer Lösung von Brom in Methanol durchzuführen. Es wird dabei lediglich das metallische Eisen gelöst, das nach Abfiltrieren der ungelöst bleibenden Oxide in bekannter Weise titrimetrisch oder photometrisch bestimmt werden kann. Der FeII-Gehalt des Oxidrückstandes kann am zweckmäßigsten nach dem Vanadat-Titrationsverfahren von Wilson bestimmt werden. Die Umsetzung mit elementarem Chlor bei etwa 400°C überführt zwar das metallische Eisen quantitativ in FeCl3, wandelt aber auch ein Drittel der als FeII-Oxid vorliegenden Eisenmenge in die gleiche Verbindung um. Somit ist dieser Weg für die direkte Bestimmung des Fe (met.)-Gehaltes nicht geeignet, stellt aber eine brauchbare Kontrolle der nach dem erstgenannten Verfahren erhaltenen Summe für Fe(met.) + FeII dar.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 135 (1952), S. 321-332 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Zusammenfassung Zusammenfassend ist zu sagen, daß die alkalimetrische Titration der Orthophosphorsäure infolge ihrer Unmittelbarkeit — sofern anwendbar — vor allen anderen Analysenverfahren den Vorzug verdient. Die erreichbare Genauigkeit liegt bei Berücksichtigung und möglichstem Ausschluß der Kohlensäure und beim Arbeiten unter günstigsten Konzentrationsverhältnissen bei Anwendung elektrischer Indication bei ±0,3%. Auf die Möglichkeit der Verwendung von Farbindicatoren bei geeigneter Arbeitsweise wird hingewiesen.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 186 (1962), S. 187-193 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary This paper shows the possibilities for electrical indication of complexometric titrations, discussing in detail the potentiometry, amperometry, voltammetry as well as the conductometry. It furthermore deals with a new indication system by means of a polarized oxide electrode and reports on the first results obtained when using this system for titrating Bi.
    Notes: Zusammenfassung Es werden die Möglichkeiten für die elektrische Indikation komplexometrischer Titrationen aufgezeigt und dabei im einzelnen die Potentiometrie, die Amperometrie, die Voltammetrie und die Konduktometrie diskutiert. Über ein neuartiges Indikationsverfahren, das sich einer polarisierten Oxidelektrode bedient, wird berichtet; erste damit bei der Titration von Bi erhaltene Ergebnisse werden mitgeteilt.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 334 (1964), S. 15-20 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The precipitation of diphosphate from solutions of secondary alkali diphosphates by means of Ba2+ yields the acid salt Ba7H2P8O28·6H2O. With increasing alkalinity of the solutions, the hydrogen ion content of the Ba salt precipitate decreases. Precipitation from Na4-diphosphate solutions yields the neutral Ba2P2O7·1,5 H2O. From X-ray investigations (no structural differences between the two precipitates being found) it in concluded that the “neutral” Ba diphosphate has a phase range from Ba:H = 2:0 to 7:2.
    Notes: Ba2+ bildet-im Unterschied zu vielen anderen zweiwertigen Metallen-bei der Fällung aus Lösungen sekundärer Diphosphate ein saures Diphosphat, Ba7H2P8O28·6H2O. Mit steigender Alkalität der Fällungslösung nimmt die Acidität der Ba-Verbindung ab. Das neutrale Na-Diphosphat entsteht nur bei der Fällung aus quaternären Diphosphat-Lösungen. Bemerkenswerterweise besteht kein struktureller Unterschied zwischen den sauren Verbindungen und dem quaternären Salz, was zu der Annahme führt, daß das quaternäre Ba-Diphosphat eine Phasenbreite zwischen Ba:H = 2:0 und 7:2 besitzt.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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