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Digitale Medien

Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures (1984)

Singh, P. ; Macleod, I. D. ; Parker, A. J.

Springer

Journal of solution chemistry 13 (1984), S. 103-119

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ISSN: 1572-8927

Schlagwort(e): Conductance ; Walden product ; tetraphenylarsonium and tetraphenylboride ions ; pyridine-water and acetonitrile-water mixtures ; alkali metal salts ; copper salts ; ion-solvent interactions ; structural effects

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The limiting conductance of various salts of Na+, Ag+, Cu+, Cu2+ and Ph4As+ in acetonitrile-water (AN-H2O) and pyridine-water (Py−H2O) mixtures are reported. Single ion values are calculated for AN-H2O mixtures using the TATB assumption [λo(Ph 4 As +) = λo(Ph 4 B −)]. The trends observed for the limiting Walden products (λoη) of the electrolytes and individual ions are discussed in terms of specific ion-solvent interactions and the structural effects of the solvent mixtures.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00646043

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