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  • 1980-1984  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Solid state phenomena Vol. 138 (Mar. 2008), p. 283-302 
    ISSN: 1662-9779
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Physics
    Notes: Using the self-consistent field approximation, the static concentration waves approachand the Onsager-type kinetics equations, the descriptions of both the statistical thermodynamics andthe kinetics of an atomic ordering of D019 phase are developed and applied for h.c.p.-Ti–Al alloy.The model of order–disorder phase transformation describes the phase transformation of h.c.p. solidsolution into the D019 phase. Interatomic-interaction parameters are estimated for bothapproximations: one supposes temperature-independent interatomic-interaction parameters, whilethe other one includes the temperature dependence of interchange energies for Ti–Al alloy. Thepartial Ti–Al phase diagrams (equilibrium compositions of the coexistent ordered α2-phase anddisordered α-phase) are evaluated for both cases. The equation for the time dependence of D019-type long-range order (LRO) parameter is analyzed. The curves (showing the LRO parameterevolution) are obtained numerically for both temperature-independent interaction energies andtemperature-dependent ones. Temperature dependence of the interatomic-interaction energiesaccelerates the LRO relaxation and diminishes a spread of the values of instantaneous andequilibrium LRO parameters versus the temperature. Both statistical-thermodynamics and kineticsresults show that equilibrium LRO parameter for a non-stoichiometry (where an atomic fraction ofalloying component is more than 0.25) can be higher than for a stoichiometry at high temperatures.The experimental phase diagram confirms the predicted (ordered or disordered) states for h.c.p.-Ti–Al
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1662-9779
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Physics
    Notes: Using both the statistical-thermodynamics methods within the scope of the selfconsistentfield approximation and the diffraction data on coherent (or diffuse) scattering of X-rays(or thermal neutrons) from (dis)ordered f.c.c.-Ni–Fe alloys of various compositions, the estimationof interatomic interactions (including their magnetic contribution) and their temperature–concentration dependences were obtained. Based on the static concentration-wave representation,the expressions for configuration free energies of L12-Ni3Fe-type permalloy, L10-NiFe-type elinvarand L12-Fe3Ni-type invar were analyzed, considering explicit expressions for configuration entropiesof atomic and magnetic subsystems with their configuration internal energies. Phase diagramof a system at issue was plotted within the field of the presence of f.c.c.-Ni–Fe alloys; their phaseboundaries, equilibrium (static) properties near critical points (order parameter, etc.), and possiblemicrostructures developed by composition-controlled magnetic transitions and/or order–disorderconstant-composition solid–solid phase transformations were discussed. The obtained results werecompared with available experimental data
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 47 (1984), S. 239-246 
    ISSN: 1432-0819
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A magnetotelluric survey was carried out in order to contribute to the definition of the deep structure of the Phlegraean Fields area affected by the bradyseismic crisis begun in the summer 1982. In a preliminary campaign carried out in autumn 1983, the MT measurements were made in eight sites, located between 0.3 and 5 km from the Harbour of Pozzuoli and affected by different degrees of uplift. In a second campaign (autumn, 1984) seven of the first eight MT soundings were repeated and four new sites were investigated, one of which located in a stable zone 10 km away from Pozzuoli. MT measurements show the presence of a thick conductive layer (ρ〈1 Ωm) thinned underneath the town of Pozzuoli, where its top reaches the minimum depth (1.2–2 km). The upper horizon of this layer has a greater concavity than that produced by surface deformation. Below the conductive layer, the substratum became progressively more resistive with depth. This resistive basement is well defined in the soundings located far away from Pozzuoli. Here, on the contrary, a zone or body much more conductive than its surroundings is detected. This conductive body could correspond to a high temperature magmatic intrusion, probably already solidified, with a rough cylindrical shape with a base diameter of 1.5±0.5 km. Introducing into the obtained model the depth of the conductive horizon desumed from the deep geothermal wells, the top of the intrusive body would lye at 3–4 km depth. A small uplift of this body related to tectonic readjustments eventually induced by strong earthquakes recently occurred in near zones could explain the surface deformation observed during the present bradyseismic crisis.
    Type of Medium: Electronic Resource
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