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Thermodynamics of electrolytes. Binary mixtures formed from aqueous NaCl, Na2SO4, CuCl2, and CuSO4, at 25°C (1976)

Downes, Colin J. ; Pitzer, Kenneth S.

Springer

Journal of solution chemistry 5 (1976), S. 389-398

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ISSN: 1572-8927

Keywords: Activity coefficients ; cupric chloride ; cupric sulfate ; electrolytes ; osmotic coefficients ; sodium chloride ; sodium sulfate

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Osmotic coefficients to high ionic strengths are reported for five of the binary mixtures formed from NaCl, Na2SO4, CuCl2, and CuSO4; the sixth system studied, NaCl−Na2SO4, is one studied by Wu, Rush, and Scatchard. The equations recently developed by Pitzer are used successfully in the interpretation of the experimental results. Revised values are given for the activity and osmotic coefficients for pure CuSO4 and CuCl2 solutions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00646413

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