ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Sodium cellulosates were prepared by reacting premercerized cotton fabrics with sodium salts of selected alcohols. The degree of conversion to the cellulosate was related to the Taft polar substituent constant, σ*, of the alkoxide R group. Increase in size of the R group in the alkanol series did not decrease the degree of cellulosate formation. The extent of reaction of the cellulosates with 2-chloroethylidiethylamine in tertiary butanol to form diethylaminoethyl cellulose (DEAE-cotton) did not increase with the sodium ion content of the starting cellulosate substrate.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1972.070160208
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