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  • 2005-2009
  • 1965-1969  (3)
  • 1945-1949
  • Chemical Engineering  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 986-994 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Capillary phenomena arising from vapor phase condensation in porous media are discussed in the light of an exact interface curvature theory and a self-consistent thermodynamic theory. The system studied consists of liquid condensed in the form of pendular rings at the contact points between identical spherical particles. The geometrical parameters - the curvature, the confined volume, and the surface area of the liquid-vapor interface - must be expressed in terms of incomplete elliptic integrals. In addition several corrections are introduced for the classical Kelvin relation for lowering of vapor pressure. One of these is based on the density dependence of the isothermal thermodynamic susceptibility. Since the susceptibility vanishes at large negative pressures, an upper limit to the curvature is established. The balance equation for the extensive free energy is considered from the point of view of hydrostatic principles.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 415-420 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A packed bed model has been adopted to develop a general correlation applicable to the flow of Newtonian fluids through all types of woven metal screens. Both of the main theoretical approaches to studying pressure drop in packed systems have been used by visualizing the screen as a collection of submerged objects with surface area to unit volume ratio a for laminar flow, and as a bundle of tubes of diameter D for turbulent flow. In the usual manner viscous and inertial energy losses are added to give an expression for the total pressure loss. Rearrangement of the general equation to the form of a friction factor yields a unique definition of the Reynolds number for screens NRe = ρu/μa2D. Procedures are described for collection of pressure drop-velocity data for the flow of nitrogen and helium through plain square, full twill, fourdrinier, plain dutch, and twilled dutch weaves. The data are used to derive a viscous resistance coefficient α = 8.61 and an inertial resistance coefficient β = 0.52. The validity of the correlation equation is tested by using additional data from the literature. The correlation successfully predicts pressure drop for a Reynolds number range of 0.1 to 1,000, void fractions from 0.35 to 0.76, screen pore diameters from 5 to 550 μ, mesh sizes from 30 to 2,400 wires/in., and surface area to unit volume ratios from 1,200 to 29,000 ft.-1.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 657-662 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presents theoretical studies of a method of using a radioactive tracer technique to evaluate the kinetic data of heterogeneous catalytic reactions that are coupled with a Knudsen type of pore diffusion. By superimposing a transient radioactive tracer response over the steady state concentration profile in the catalyst particle, one can establish an implicit relation between the total amount of radioactive components diffused out of the particle and the kinetic data of the reaction system. This relation can then be used to evaluate kinetic data of the reaction system. A detailed study of general monomolecular complex systems is given. Use of the method for nonlinear systems is also included.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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