ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Cyclic Compounds Made of Phosphorus, Carbon, and SulfurBy reaction of P4S10 with excess tri-n-dodecylamine and tribenzylamine bis(didodecylammonium)-3,6-diundecyl-2,5-dithioxo-1,4,2λ5,5λ5-dithiaphosphorinan-2,5-disulfide (IId) and bis(tribenzylammonium)-3,6-diphenyl-2,5-dithioxo-1,4,2λ5,5λ5-dithiaphosphorinan-2,5-disulfide (IIe), respectively, are formed. Reactions of the ammonium-3,6-dialkyl-2,5-dithioxo-1,4,2λ5,5λ5-dithiaphosphorinan-2,5-disulfides with aqueous alkali solutions and CH3I as well as their therolysis are described.
Notes:
Bei der Umsetzung von P4S10 mit überschüssigem Tri-n-dodecylamin und Tribenzylamin entstehen Bis(didodecylammonium)-3,6-diundecyl-2,5-dithioxo-1,4,2λ5,5λ5-dithiadiphosphorinan-2,5-disulfid (IId) bzw. Bis(tribenzylammonium)-3,6-diphenyl-2,5-dithioxo-1,4,2λ5,5λ5-dithiadiphosphorinan-2,5-disulfid (IIe). Reaktionen der Ammonium-3,6-dialkyl-2,5-dithioxo-1,4,2λ5,5λ5-dithiadiphosphorinan-2,5-disulfide mit wäßrigen Alkalilösungen und CH3I sowie ihre Thermolyse sind beschrieben.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19905840116
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