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  • 2000-2004
  • 1990-1994  (1)
  • Concave base / Macrocycle / 1,10-Phenanthroline / Cyclophane / Aryl lithium compounds  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Concave Reagents, 5 Bimacrocyclic 1,10-Phenanthroline Cyclophanes (1990)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 643-645 
    Details
    ISSN: 0009-2940
    Keywords: Concave base / Macrocycle / 1,10-Phenanthroline / Cyclophane / Aryl lithium compounds ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The addition of lithium aryls 3 to 1,10-phenanthroline (2), functionalization of the rearomatized bisadduct 8b to the tetraphenol 8d, and cyclization of 8d with two equivalents of an α,ω-ditosylate 9 led to a highly symmetrical, conformer-free bimacrocyclic 1,10-phenanthroline 10a in which the basic and coordinating region possesses a concave shielding.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19901230335
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