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  • 2000-2004  (2)
  • 1990-1994  (2)
  • global convergence  (2)
  • kinetics  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Are cell redox or lactate dehydrogenase kinetics responsible for the absence of gluconeogenesis from lactate in sea raven, hepatocytes? (1994)
    Springer
    Fish physiology and biochemistry 13 (1994), S. 59-67 
    Details
    ISSN: 1573-5168
    Keywords: fish ; sea raven ; gluconeogensis ; hepatocytes ; redox ; LDH ; isozymes ; kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Previous studies have reported very low rates of gluconeogenesis from lactate in sea raven (Hemitripterus americanus) hepatocytes compared to other teleosts studied. This study examines whether hepatic cell redox or lactate dehydrogenase (LDH) characteristics may explain this observation. Sea raven hepatic optimal LDH activities (pyruvate reductase direction) were more than 40 times less compared with rainbow trout liver values (40 vs 1914 μmol·min−1·g−1 protein). The Km(lactate) was 9.24 and 0.86 mM for sea raven and trout hepatic LDH, but the Km(pyruvate) was similar between the two species (0.11 and 0.21 mM, respectively). These results suggested that sea raven liver LDH did not favour lactate use and was more indicative of the mammalian M-isozyme. Gel electrophoresis showed a predominant intermediate isozyme, with a small amount of the M-type LDH. Phosphoenolpyruvate carboxykinase (PEPCK) was localized to the mitochondrial compartment, while there was no apparent mitochondrial glutamate-oxaloacetate transaminase (GOT) activity. No in vitro lactate flux to glucose was found in untreated, 10 mM ethanol-treated, or 3 mM NH4Cl-treated sea raven hepatocytes, although CO2 production from lactate was decreased by ethanol and increased by NH4Cl. These results provide evidence that cell redox does not limit gluconeogenesis from lactate, while low activities and the kinetic characteristics of LDH may partially explain the low lactate gluconeogenesis reported in sea raven hepatocytes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00004120
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Studies on Non-isothermal Kinetics of the Thermal Decomposition of Eu2(BA)6(bipy)2 (2000)
    Springer
    Journal of thermal analysis and calorimetry 62 (2000), S. 747-755 
    Details
    ISSN: 1572-8943
    Keywords: benzoic acid ; europium complex ; kinetics ; non-isothermal ; thermal decomposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermal decomposition of Eu2(BA)6(bipy)2 (BA=C2H5N– 2, benzoate; bipy=C10H8N2, 2,2'-bipyridine)and its kinetics were studied under the non-isothermal condition by TG-DTG, IR and SEM methods. The kinetic parameters were obtained from analysis of the TG-DTG curves by the Achar method, the Madhusudanan-Krishnan-Ninan (MKN) method, the Ozawa method and the Kissinger method. The most probable mechanism function was suggested by comparing the kinetic parameters. The kinetic equation for the first stage can be expressed as: dα/dt=Aexp(–E/RT)3(1–α)2/3.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1026785727479
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Projected quasi-Newton algorithm with trust region for constrained optimization (1990)
    Springer
    Journal of optimization theory and applications 67 (1990), S. 369-393 
    Details
    ISSN: 1573-2878
    Keywords: Two-sided projected Hessians ; trust regions ; differentiable penalty functions ; global convergence ; two-step Q-superlinear rate ; constrained optimization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract In Ref. 1, Nocedal and Overton proposed a two-sided projected Hessian updating technique for equality constrained optimization problems. Although local two-step Q-superlinear rate was proved, its global convergence is not assured. In this paper, we suggest a trust-region-type, two-sided, projected quasi-Newton method, which preserves the local two-step superlinear convergence of the original algorithm and also ensures global convergence. The subproblem that we propose is as simple as the one often used when solving unconstrained optimization problems by trust-region strategies and therefore is easy to implement.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00940481
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Globally Convergent Inexact Generalized Newton Method for First-Order Differentiable Optimization Problems (2000)
    Springer
    Journal of optimization theory and applications 106 (2000), S. 551-568 
    Details
    ISSN: 1573-2878
    Keywords: nonsmooth optimization ; inexact Newton methods ; generalized Newton methods ; global convergence ; superlinear rate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract Motivated by the method of Martinez and Qi (Ref. 1), we propose in this paper a globally convergent inexact generalized Newton method to solve unconstrained optimization problems in which the objective functions have Lipschitz continuous gradient functions, but are not twice differentiable. This method is implementable, globally convergent, and produces monotonically decreasing function values. We prove that the method has locally superlinear convergence or even quadratic convergence rate under some mild conditions, which do not assume the convexity of the functions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1004605428858
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    Paper (German National Licenses)
    Fulltext
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