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  • 2000-2004
  • 1985-1989  (6)
  • 1980-1984  (2)
  • Tait equation  (5)
  • specific volume  (4)
  • dodecanol
Materialart
Erscheinungszeitraum
  • 2000-2004
  • 1985-1989  (6)
  • 1980-1984  (2)
  • 1990-1994  (1)
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 10 (1989), S. 857-870 
    ISSN: 1572-9567
    Schlagwort(e): compressibility ; density ; fluorocarbon oil ; free-volume equation ; high pressure ; perfluoropolyether ; specific volume ; Tait equation ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract New experimental data on the density and viscosity of linear, unbranched perfluoropolyethers are presented at temperatures from 273 to 333 K and pressures up to 180 MPa. The measurements were carried out by a high-pressure burrette apparatus and a falling-cylinder viscometer. The uncertainties of the measurements are estimated to be less than 0.09% for the specific volume and 2.5% for the viscosity. The P-V data at each temperature are correlated satisfactorily by the Tait equation. The viscosity data are also analyzed and correlated with pressure or molar volume by several empirical and theoretical equations.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 3 (1982), S. 201-215 
    ISSN: 1572-9567
    Schlagwort(e): density ; isothermal compressibility ; Tait equation ; thermal conductivity ; thermal expansion coefficient ; toluene ; transient hot-wire method
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract New experimental data on the thermal conductivity and the density of liquid toluene are presented in the temperature range 0–100°C at pressures up to 250 MPa. The measurements of thermal conductivity were performed with a transient hot-wire apparatus on an absolute basis with an inaccuracy less than 1.0%. The density was measured with a high-pressure burette method with an uncertainty within 0.1%. The experimental results for both properties are represented satisfactorily by the Tait-type equations, as well as empirical polynomials, covering the entire ranges of temperature and pressure. Furthermore, it is found that simple relations exist between the temperature dependence of thermal conductivity and the thermal expansion coefficient, and also between the pressure dependence of thermal conductivity and the isothermal compressibility, as are suggested theoretically.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 8 (1987), S. 147-163 
    ISSN: 1572-9567
    Schlagwort(e): alcohols ; aqueous alcohol solutions ; ethanol ; free-volume theory ; methanol ; 2-methyl-2-propanol ; pressure effect ; propanol ; Tait equation ; t-butyl alcohol ; viscosity ; water
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract New experimental viscosity data are presented for aqueous solutions of methanol, ethanol, 1-propanol, 2-propanol, and 2-methyl-2-propanol (t-butyl alcohol) in the temperature range from 283 to 348 K and pressures up to 120 MPa. The viscosity measurements were performed using a falling-cylinder viscometer on a relative basis with an uncertainty of less than 2%. The viscosity of pure alcohols and aqueous solutions is found to increase almost linearly with increasing pressure, whereas that of water decreases slightly with pressure at temperatures below 298 K. As for the composition dependence of the viscosity, a distinct maximum appears near 0.3–0.4 mole fraction of alcohol on all isobars at each temperature. The viscosity maximum shifts gradually to a higher alcohol concentration with increasing temperature and pressure. The isobars of aqueous 2-propanol and 2-methyl-2-propanol solutions have another shallow minimum near 0.9 mole fraction of alcohol below 323 K. The experimental results were analized empirically by a Tait-type equation and a free-volume theory. It was found that the isothermal viscosity data were satisfactorily correlated by these equations as functions of pressure and composition or of density and composition.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 9 (1988), S. 85-101 
    ISSN: 1572-9567
    Schlagwort(e): Benedict-Webb-Rubin (BWR) equation ; 1-chloro-1,2,2,2-tetrafluoroethane ; compressibility factor ; critical pressure ; critical temperature ; equation of state ; R124 ; specific volume ; vapor pressure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The critical temperature and pressure, vapor pressure, and PVT relations for gaseous and liquid 1-chloro-1,2,2,2-tetrafluoroethane (R124) were determined experimentally. The vapor pressure was measured in the temperature range from 278.15 K to the critical temperature. The PVT measurements were carried out using two types of volumeters in the temperature range from 278.15 to 423.15 K, at pressure up to 100 MPa. The numerical PVT data of gaseous state are fitted as a function of density to a modified Benedict-Webb-Rubin equation. The pressure-volume relations of the liquid at each temperature are correlated satisfactorily as a function of pressure by the Tait equation. The critical density and saturated vapor and liquid densities are also determined and some of the thermodynamic properties are derived from the experimental results.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 10 (1989), S. 833-843 
    ISSN: 1572-9567
    Schlagwort(e): decanol ; dodecanol ; falling-body viscometer ; free volume ; hexadecanol ; hexanol ; high pressure ; octanol ; significant structure theory ; tetradecanol ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Viscosities of six higher 1-alkanols (1-hexanol, 1-octanol, 1-decanol, 1-dodecanol, 1-tetradecanol, and 1-hexadecanol) have been determined at temperatures from 298 to 348 K and pressures up to 200 MPa. The viscosity measurements were performed using a falling-body viscometer with an uncertainty of ±5%. Simple equations are presented to express the experimental viscosities as a function of temperature and pressure within the experimental uncertainty. The relationship between the viscosity and the density of these alkanols is discussed in terms of the significant structure theory extended to high pressures.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 10 (1989), S. 885-897 
    ISSN: 1572-9567
    Schlagwort(e): decanol ; density ; dodecanol ; hexadecanol ; hexanol ; high pressure ; isothermal compressibility ; octanol ; Tait equation ; tetradecanol ; thermal expansion coefficient
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Molar volumes, thermal expansion coefficients, and isothermal compressibilities of six higher 1-alkanols (1-hexanol, 1-octanol, 1-decanol, 1-dodecanol, 1-tetradecanol, and 1-hexadecanol) have been determined at temperatures from 298 to 348 K and pressures up to 40 MPa. The density measurements were performed using a vibrating densitometer with an uncertainty of ±0.06%. The relationship between the properties and the structures of these alkanols is discussed in terms of the carbon-chain lengths.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 4 (1983), S. 283-294 
    ISSN: 1572-9567
    Schlagwort(e): compressibility factor ; database system: density ; dielectric constant ; refractive index ; retrieval program ; specific enthalpy ; specific entropy ; specific heat capacity ; specific volume ; surface tension ; thermal conductivity ; vapor pressure ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A new database system was designed and constructed in order to provide the newest and most reliable numerical data on thermophysical properties of fluids to the scientific and technical community as quickly as possible. The database is concerned with 12 kinds of property data: density, specific volume, compressibility factor, vapor pressure, specific heat, specific enthalpy, specific entropy, viscosity, thermal conductivity, surface tension, refractive index, and dielectric constant of 340 pure fluids under all conditions of seven convenient physical states. Only the most probable data, which were critically evaluated in advance, are compiled as functions of temperature and pressure in the form of either numerical data tables or correlation formulas. Property values at desired grid points of temperature and pressure can be obtained in SI units directly or by interpolations with some supplementary information, such as the grade of reliability, source bibliography, and fundamental physical constants of the fluid. The database is usable as conversational processing by TSS, the tabulation of property data in a batch processing, and one of the subroutine libraries in the computation of a user's program. Ten kinds of application programs are prepared for multipurpose retrievals so that anyone can use the database without any special knowledge of the structure or machine languages of this system.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    International journal of thermophysics 8 (1987), S. 47-70 
    ISSN: 1572-9567
    Schlagwort(e): alcohols ; aqueous mixtures ; butanols ; compressibility ; ethanol ; excess volume ; high pressure ; methanol ; propanols ; specific volume ; Tait equation ; water
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The specific volumes of C1-C4 alcohols and binary mixtures of water with methanol, ethanol, 1-propanol, 2-propanol, and 2-methyl-2-propanol are presented as functions of temperature, pressure, and composition. The measurements were carried out using a modified Adams piezometer and a high-pressure burette method in a temperature range from 283.15 to 348.15 K at pressures up to 350 MPa. The uncertainties in the specific volume obtained are estimated to be less than 0.09%. The specific volumes of the pure alcohols and their mixtures with water are found to decrease monotonously with increasing pressure. The numerical P-V relations at each temperature and composition are correlated satisfactorily as a function of pressure by the Tait equation. Definite inflections appear on the isobars of isothermal compressibility or partial molar volume versus composition of alcohol + water mixtures.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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