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  • 2000-2004  (2)
  • 1985-1989  (8)
  • 1965-1969  (1)
  • 1960-1964
  • Polymer and Materials Science  (6)
  • Organic Chemistry  (3)
  • AMS Classification. Primary 57R56; Secondary 68Q05, 81Q70, 82B10, 94B99, 20F36.
  • HIV
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Material
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Year
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  • 1
    Electronic Resource
    Electronic Resource
    Quantum Computation and the Localization of Modular Functors (2001)
    Springer
    Foundations of computational mathematics 1 (2001), S. 183-204 
    Details
    ISSN: 1615-3383
    Keywords: AMS Classification. Primary 57R56; Secondary 68Q05, 81Q70, 82B10, 94B99, 20F36.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract. The mathematical problem of localizing modular functors to neighborhoods of points is shown to be closely related to the physical problem of engineering a local Hamiltonian for a computationally universal quantum medium. For genus =0 surfaces, such a local Hamiltonian is mathematically defined. Braiding defects of this medium implements a representation associated to the Jones polynomial and this representation is known to be universal for quantum computation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s102080010006
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  • 2
    Electronic Resource
    Electronic Resource
    Structure and properties of p-carboxysuccinanilic polyester resins (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 35 (1988), S. 75-83 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyester resins were prepared by the reaction of p-carboxysuccinanilic acid ethyl ester with ethylene glycol and 1,4-butenediol. Also, unsaturated polyester resins were prepared by the copolymerization of p-carboxysuccinanilic acid ethyl ester and maleic anhydride with ethylene glycol, 1,6-hexanediol, 1,4-butenediol, and 2-butyne-1,4-diol. All the polyester resins and the copolyesters have been characterized and were found to cure with styrene, except those prepared in the absence of maleic anhydride. The properties of the cured products in the form of films were determined. Infrared and nuclear magnetic resonance (NMR) spectroscopy were used for both qualitative and quantitative analyses of the polyester resins and their hydrolyzate products after curing with styrene.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1988.070350107
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  • 3
    Electronic Resource
    Electronic Resource
    Microanalysis of polymers using a windowless energy-dispersive X-ray detector (1988)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 26 (1988), S. 201-206 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The surface compositions of various polymeric films, grown electrochemically on platinum foils, have been investigated by energy-dispersive x-ray analysis in conjunction with scanning electron microscopy (SEM/EDS). Comparison of the relative area ratios of peaks for the C and N Kemission lines show that the EDS may be used to study the surface composition of polymers. The evidence presented strongly suggests that there is limited structural degradation and the elemental composition is not changed under the electron beam at relatively low accelerating voltages. This technique statistically samples the repeat units of the polymer. For samples grown in both aqueous and nonaqueous solutions. SEM/EDS provides evidence for extensive contamination with oxygen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1988.080260120
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  • 4
    Electronic Resource
    Electronic Resource
    Reductions in Salivary Cortisol Are Associated with Mood Improvement During Relaxation Training Among HIV-Seropositive Men (2000)
    Springer
    Journal of behavioral medicine 23 (2000), S. 107-122 
    Details
    ISSN: 1573-3521
    Keywords: salivary cortisol ; relaxation ; HIV ; mood
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Psychology
    Notes: Abstract This study examined salivary cortisol and mood during relaxation training in 30 symptomatic, HIV+ gay men participating in a 10-week, group-based cognitive-behavioral stress management intervention. Cortisol levels and mood were assessed within these sessions just before and after 45-min relaxation exercises given as part of each session. Participants also recorded their stress level and compliance with daily home relaxation practice. Presession cortisol levels decreased across the 10-week period and were related to decreases in global measures of total mood disturbance and anxious mood. Reductions in presession cortisol levels were also associated with decreases in self-reported stress level during home practice. Greater reductions in cortisol during the first three sessions were associated with more frequent relaxation practice at home. These findings suggest that salivary cortisol represents an objective neuroendocrine marker for changes in anxiety and distress observed during relaxation training in symptomatic, HIV-seropositive men.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1005419917023
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  • 5
    Electronic Resource
    Electronic Resource
    Hydrogen-bonding. Part 4. An analysis of solute hydrogen-bond basicity, in terms of complexation constants (log K), using F1 and F2 factors, the principal components of different kinds of basicityPart 3. M. H. Abraham, P. P. Duce, D. V. Prior, R. A. Schulz, J. J. Morris and P. J. Taylor, J. Chem. Soc. Faraday Trans. 1, 84, 865 (1988). (1989)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 2 (1989), S. 243-254 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The principal components factors F1 and F2 in the equation \documentclass{article}\pagestyle{empty}\begin{document}$$ \log K = {\rm BDP}_0 + S_1 F_1 + S_2 F_2 $$\end{document} have been used to obtain S1 and S2 values for sets of hydrogen-bond bases against 32 reference acid/solvent systems. The constants S1 and S2 define an angle θ = tan-1 S2/S1 that is a measure of the electrostatic:covalent bonding ratio in the hydrogen-bond complex. It is shown that θ can vary from 53 (4-fluorophenol in CH2Cl2)to 86 degrees (Ph2NH in CCl4) depending on the reference acid and solvent. This variation in θ can lead to family dependent behaviour in plots of log K for bases against a given reference acid system vs log K for bases against another reference acid system, and precludes the construction of any general scale of hydrogen-bond basicity using log K values. Amongst a quite wide range of reference acid/solvent systems θ varies only from 64 to 73 degrees, and for bases against these reference systems a ‘reasonably general’ scale could be set up. Such a scale could be extended to bases against reference acid/solvent systems outside the 64-73 degree range provided that certain classes of base (e.g. pyridines, alkylamines) were excluded from the additional reference acid/solvent systems.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610020307
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  • 6
    Electronic Resource
    Electronic Resource
    Hydrogen-bonding 8.Part 7; M. H. Abraham, P. L. Grellier, D. V. Prior, P. P. Duce, J. J. Morris and P. J. Taylor. J. Chem Soc., Perkin Trans. 2, (in press). Possible equivalence of solute and solvent scales of hydrogen-bond basicity of non-associated compounds (1989)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 2 (1989), S. 540-552 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Using the solvatochromic indicator method, a scale of solvent hydrogen-bond basicity, β1 (General), has been set up using a series of double regression equations, \documentclass{article}\pagestyle{empty}\begin{document}$$ \nu = \nu _0 + s\pi _1^* + b\beta _1 $$\end{document} for 11 aniline-type indicators. A similar solvent scale, β1 (Special), has been constructed by the homomorphic comparison method using only results by Laurence et al. on the indicators 4-nitroaniline and 4-nitro-N,N-dimethylaniline. Results are available from our previous work on a general solute scale, β2H, and we have also obtained a special solute scale, β2 (pKHB) from available log K values for hydrogen-bond complexation of bases with 4-fluorophenol in CCl4. However, the two solute β2 scales are virtually identical.It is shown that there is a general connection between β1(General) and β2H, with r = 0·9775 and s.d. = 0·05 for 32 compounds, and between β1(Special) and β2H, with r = 0·9776 and s.d. = 0·06 for the same 32 compounds. The latter correlation over 60 compounds yields r = 0·9684 and s.d. = 0·07. However, there are so many compounds in these regressions for which the differences in the solvent and solute β values are larger than the total expected error of 0·07 units that the use of β1 to predict β2 or vice versa is a very hazardous procedure. About 70 new β1 values obtained by the double regression method are also reported.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610020706
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  • 7
    Electronic Resource
    Electronic Resource
    Solute-solvent interactions in chemical and biological systems. IV. Correlations of ΔG, ΔH and TΔS of transfer of aliphatic and aromatic solutes from 2,2,4-trimethylpentane to aqueous solution (1989)
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 2 (1989), S. 559-564 
    Details
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: ΔG, ΔH and TΔS of transfer of 25 aliphatic and aromatic solutes from 2,2,4-trimethylpentane to aqueous buffer (pH 7) at 298 K have been examined in terms of intrinsic volumes and the solvatochromic parameters π*, δ, β and α of the pure solutes Correlations of the form \documentclass{article}\pagestyle{empty}\begin{document}$$ XYZ = XYZ_0 + {{mV_{\rm I} } \mathord{\left/ {\vphantom {{mV_{\rm I} } {100}}} \right. \kern-\nulldelimiterspace} {100}} + s\pi ^* + d\delta + d\beta + a\alpha $$\end{document} indicate that the thermodynamic quantities of transfer are unequally affected by solute properties; most notably, for aromatic solutes the cavity term mVI/100 is a principal (unfavorable) factor affecting TΔS, but has little effect on ΔH. Transfer to water is favored by increasing solute π* (dipolarity-polarizability), β (H-bond basicity) and α (H-bond acidity), because water has greater dipolarity, H-bond acidity and H-bond basicity than trimethylpentane. Hydrogen bonding contributes exothermically to ΔH, but unfavorably to TΔS, as would be expected from a loss of transitional entropy. Correlations of ΔG, ΔH and TΔS with solute VI/100, β, α, μ2 and polarizability function [(n2 - 1)/(n2 + 2)] give closely comparable results.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/poc.610020708
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  • 8
    Electronic Resource
    Electronic Resource
    Synthesis, crosslinking and degradation of some unsaturated polyester resins (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 1117-1124 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Some unsaturated polyester resins were prepared by the ester interchange between p-carbethoxymaleananilic acid and p-carbethoxysuccinanilic acid with saturated and unsaturated diols. Moreover, copolymers were also synthesized by the polyesterification of the aforementioned acids and maleic anhydride with the above-mentioned glycols. The structure of both the unsaturated polyester resins and copolymer resins was established by IR, UV, and NMR spectroscopy. Also, viscosity measurements and molecular weight determinations were further tools for their structural elucidation. All the products were attempted to cure with styrene in the presence of benzoyl peroxide as initiator, and the produced network structures, in the form of films, were tested as surface coating materials for glass and metals. The structure of the cured products was established after their degradation, by physical and spectroscopical means.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070340320
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  • 9
    Electronic Resource
    Electronic Resource
    Preparation and testing of local polyester composites based on unsaturated polyesters as binder (1986)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 31 (1986), S. 2705-2710 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A series of polymeric composites were prepared with sand/polyester ratio 92:8%. The sand used was local one. The polymeric composites were tested for their compressive strength, exterior volume, porosity, water uptake, specific gravity, volume of open pores and bulk density. The mechanical properties of these polymeric composites were within the range required for building bricks. No significant differences were observed between the polymeric composites made of glass sand and those from untreated sand except in exterior volume and compressive strength. Medium untreated sand was found to give better results in the mechanical properties.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1986.070310825
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  • 10
    Electronic Resource
    Electronic Resource
    Einsatz von Cross-flow-Techniken in der BioverfahrenstechnikVortrag von M. H. Kopf auf dem Jahrestreffen der Verfahrens-Ingenieure, 21. bis 23. Sept. 1988 in Hannover. (1989)
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 61 (1989), S. 459-468 
    Details
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Use of cross-flow techniques in biotechnology. This progress report summarises experience and results gained during the development and optimisation of various micro- and ultrafiltration process. The major emphasis lies on the calculation of data which precede actual separation experiments and which define the separation or work-up problem and the product system involved. To this end the author presents a checklist covering the following areas: definition of the problem at hand, characterisation of the product system and demands placed on membrane plant and membranes. The second area of emphasis is the concept of a flexible membrane test plant. With the aid of this plant, all the data necessary for design and optimisation of a membrane process can be worked out during the laboratory experimentation phase. The principal process engineering tools available for optimisation of the specific filtration performance and maximisation of the product yield are considered. The report considers both the effects and the theoretical fundamentals of techniques for maintaining steady flow of filtrate and for avoiding nonspecific adsorption.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cite.330610607
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