ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The cleavage of poly(vinyl alcohol) in dimethyl sulfoxide at 42°C has been measured viscometrically in the presence of tert-butyl hydroperoxide and metal complexes. Phthalocyanine complexes of copper(II), iron(III), cobalt(II), and vanadium as VO(II) as well as hemin, hematin, chlorophyllin, and cytochrome c were used. The rates of decomposition of tert-butyl hydroperoxide in the presence of these metal complexes were measured idometrically. These data are compared to results obtained with other metal complexes in similar reactions.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1976.170140505
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