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Cleavage of poly(vinyl alcohol) in the presence of tert-butyl hydroperoxide and biologically active metal complexes (1976)

Jochsberger, T. ; Auerbach, A. ; Indictor, N.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 1083-1087

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Details

ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The cleavage of poly(vinyl alcohol) in dimethyl sulfoxide at 42°C has been measured viscometrically in the presence of tert-butyl hydroperoxide and metal complexes. Phthalocyanine complexes of copper(II), iron(III), cobalt(II), and vanadium as VO(II) as well as hemin, hematin, chlorophyllin, and cytochrome c were used. The rates of decomposition of tert-butyl hydroperoxide in the presence of these metal complexes were measured idometrically. These data are compared to results obtained with other metal complexes in similar reactions.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1976.170140505

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