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  • 2000-2004  (1)
  • 1960-1964
  • AM1 method  (1)
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  • 2000-2004  (1)
  • 1960-1964
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    Electronic Resource
    Electronic Resource
    Tautomerism and vapor-phase transformations of 2-hydroxytetrahydrofuran (2000)
    Springer
    Chemistry of heterocyclic compounds 36 (2000), S. 775-778 
    Details
    ISSN: 1573-8353
    Keywords: 2-hydroxytetrahydrofuran ; 4-hydroxybutanal ; 2,3-dihydrofuran ; tautomerism ; dehydration ; AM1 method ; concerted mechanism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The relative stability of 2-hydroxytetrahydrofuran and the tautomeric 4-hydroxybutanal was determined by the semi-empirical AM1 method. It was concluded that the cyclic tautomer predominates in the gas phase at 25°C. Vapor-phase dehydration of 2-hydroxytetrahydrofuran in the presence of porcelain and silica gel L leads to a quantitative yield of 2,3-dihydrofuran.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02256908
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