ISSN:
1588-2837
Keywords:
35S, S-uptake
;
S-exchange
;
CoMo/Al2O3
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A combined radioactive flow-circulation tracer method has been developed and applied to a CoMo/Al2O3 catalyst for measurement of sulfur uptakes and of catalyst - gas phase sulfur exchange in the H2S partial pressure range of 2–47 kPa and the temperature range of 373–673 K. Equilibrium between gas-phase and catalyst sulfur species was rapidly achieved. A substantial part of the sulfur uptake was retained as adsorbed (reversible) sulfur species. The exchange of sulfur increased with increase in temperature up to 573 K and in H2S partial pressure up to 4 kPa.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010386200144
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