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Condensation of Glyoxal with Triethylenetetraamine; Isomerization and Cyclization (2000)

Hervé, Gwénaëlle ; Bernard, Hélène ; Toupet, Loïc ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 2000 (2000), S. 33-35

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Details

ISSN: 1434-193X

Keywords: Glyoxal ; Triethylenetetraamine ; Diethyl Oxalate ; Cyclen ; Ring closure ; Isomerizations ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: ---The condensation of triethylenetetraamine with glyoxal leads to the formation of four stereoisomers A, B, C, D. A is the thermodynamic product and D the kinetic one. These four compounds exhibit equilibrium and isomerization phenomena which are the key-feature of this cyclen synthesis.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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