ISSN:
1572-9028
Keywords:
manganese
;
tungsten
;
hydrogen peroxide
;
terpenes
;
epoxidation
;
cis dihydroxylation
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract This paper discusses two heterogeneous catalysts that were designed by covalent or electrostatic immobilization of a homogeneous metal complex. The first material contains Mn–triazacyclononane complexes anchored to silica. The second material is a resin with exchanged peroxo W polyoxoanions. Topics of interest include chemoselectivity, regioselectivity and recyclability. These aspects are studied in reactions with 18 different olefin substrates, with a focus on terpene reactions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009046703320
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