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Digitale Medien

Studies on Non-isothermal Kinetics of the Thermal Decomposition of Eu2(BA)6(bipy)2 (2000)

Zhang, J.-J. ; Wang, R.-F. ; Li, J.-B. ; [weitere]

Springer

Journal of thermal analysis and calorimetry 62 (2000), S. 747-755

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ISSN: 1572-8943

Schlagwort(e): benzoic acid ; europium complex ; kinetics ; non-isothermal ; thermal decomposition

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The thermal decomposition of Eu2(BA)6(bipy)2 (BA=C2H5N– 2, benzoate; bipy=C10H8N2, 2,2'-bipyridine)and its kinetics were studied under the non-isothermal condition by TG-DTG, IR and SEM methods. The kinetic parameters were obtained from analysis of the TG-DTG curves by the Achar method, the Madhusudanan-Krishnan-Ninan (MKN) method, the Ozawa method and the Kissinger method. The most probable mechanism function was suggested by comparing the kinetic parameters. The kinetic equation for the first stage can be expressed as: dα/dt=Aexp(–E/RT)3(1–α)2/3.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1026785727479

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