ISSN:
1588-2837
Keywords:
Chlorobenzene
;
hydrodechlorination
;
dispersion effect
;
support effect
;
Pd/C
;
Rh/C
;
Pt/C
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Chlorobenzene hydrodechlorination in liquid phase has been studied. Chlorine released during the reaction inhibits conversion in large metallic particles. It was found comparing the behavior of Pd/SiO2, Pd/Al2O3 and Pd/C catalysts that the support plays the role of a chlorine trap. The activity for Pt, Rh and Pd at similar dispersions corresponds to the chlorine adsorption affinity of the metals.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010354430406
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