ISSN:
1089-7623
Source:
AIP Digital Archive
Topics:
Physics
,
Electrical Engineering, Measurement and Control Technology
Notes:
A measuring system that integrates a low-temperature optical cell UV-visible (UV-Vis) for air exclusion experiments with a liquid x-ray absorption spectroscopy (XAS) cell (x-ray absorption near-edge spectroscopy and extended x-ray absorption fine structure) is reported here together with its application in studies of organometallic complexes. UV-Vis measurements are performed in a three-compartment glass vessel, fitted with an external fiber optics probe. This UV-Vis cell is suitable for the measurement of oxygen- and air-sensitive compounds at variable temperatures (RT to −78 °C). The liquid XAS cell is filled with the UV-Vis solution at low temperature and can be used in both fluorescence- or transmission-mode measurements with (frozen) solutions. The complete measuring system is reusable and easy to clean and handle. To test the performance of these cells the oxygenation behavior of a dinuclear organometallic copper(I) complex was studied in acetone by UV-Vis and XAS. It is shown that direct correlation of low-temperature UV-Vis and XAS data is possible in organic solvents. © 2002 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1494869
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