ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The Ru atom of the title compound, [Ru(C16H12N2O2)2(C10H8N2)](PF6)2, is octahedrally coordinated to the N atoms of 2-(2-pyridyl)-4-methoxycarbonylquinoline and to those of a bipyridine ligand which are cis to each other. Owing to the rigidity of the 2-(2-pyridyl)-4-methoxycarbonylquinoline ligand, the complex is a distorted octahedron with Ru—N distances of 2.119 (2), 2.062 (2) and 2.043 (2) Å. Half a complex cation and one hexafluorophosphate counter-ion form the asymmetric unit. The complex cation lies on a twofold axis running along the line joining the Ru atom and the midpoint of the C17—C17(−x, y, {1 \over 2} − z) bond.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801008765
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