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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 3848-3852 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The fluorescence intensity fluctuation and polarization modulation of spin-cast single fluorescent conjugated polymers of 2,5-dioctyloxy p-phenylene vinylene (DOO-PPV) with length of the order of the persistence length have been studied. The results indicate that this type of polymer behaves like a collection of semi-independent excitons, with dipoles aligned predominately in the same direction. This suggests that this type of polymer can be considered as a linearly extended rigid structure (i.e., a straight rod). The fluorescent transient exhibits a multiple-step-like behavior with the count rate at each step being a multiple of a common step-size. The fluorescence variation follows the excitation polarization with a DC background observable in some molecules. This DC background indicates that the chromophores in some polymers are not aligned in the same direction. Variations in the Huang–Rhys factor at a single polymer level are also observed. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Sedimentology 49 (2002), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Large-scale explosive eruptions from silicic caldera volcanoes can generate huge volumes of pyroclastic material in terrestrial and marine environments. On land, erosion, remobilization and redeposition of this debris is predominantly carried out by running water in the form of precipitation run-off. Conversely, in the submarine realm, both primary emplacement and subsequent remobilization are influenced by the presence of water as a transporting medium. Despite this, and the number of studies devoted to volcaniclastic sedimentation, relatively little attention has been paid to the hydrodynamic behaviour of the particles themselves, which ought to underpin any assessment of transport or depositional process. This is crucial, as many volcanic particles exhibit variable density: according to composition and as functions of differing degrees of vesiculation and the extent to which pore space is filled by water and/or gaseous phases during transport and deposition. Investigation of the physical and hydrodynamic properties of Taupo 1800a pumice, with reference to sedimentary facies developed during the eruption aftermath, shows that, although buoyant when dry, when sufficiently waterlogged, cool pumice clasts will sink and behave more like quartzo-feldspathic material. Saturation is apparently achieved by a combination of rapid capillary flooding of large interconnected vesicles and slower diffusional air–water exchange in smaller pores. Low saturated pumice densities result in lower settling velocities and easier entrainment by tractional currents than those for equivalent-sized quartzo-feldspathic or crystal/lithic particles. Fine-grained pumice is conversely harder to entrain because of the frictional interlocking of angular particles. These unusual properties of temporary buoyancy, variable saturation, low density and size-dependent cohesion complicate interpretations of the depositional setting and energy of pumiceous sediments and give rise to several unique facies. These findings have implications not only for the analysis of remobilized pyroclastic facies in terrestrial and marine environments, but also for primary depositional processes during subaqueous explosive volcanism.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0819
    Keywords: Stratovolcano Explosive volcanism Tephra remobilisation Lahars Ruapehu Volcanic hazards
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract. A feature of small-scale explosive volcanism at stratovolcanoes is the rapid destruction of primary near-vent pyroclastic deposits by sedimentary processes. A protracted series of explosive eruptions of moderate volume from September 1995 until July 1996 at Mount Ruapehu in New Zealand, its largest eruptive episode this century, afforded an opportunity to study these remobilisation processes in detail. All significant sub-plinian eruptions occurred in mid-winter, forming metre-thick tephra accumulations on steep slopes covered with perennial ice and seasonal snow. Subsequent events demonstrated the variety and complexity of the erosion processes that remobilise primary pyroclasts in such a setting. These processes arose from the complex interactions of tephra with snow and ice, and liquid water in varying proportions, and were very diverse in nature and scale. Their effectiveness can be gauged from the fact that there is almost no stratigraphic record of any of the 〉40 eruption episodes recorded in the past 100 years at Ruapehu. Syn-eruptive remobilisation processes included the generation of eruption-triggered lahars by the ejection of hot water from the Crater Lake. Post-eruptive interactions mainly remobilised fall deposits from proximal areas, and included rain-triggered lahars, which were among the largest and most hazardous events with the greatest distal impacts.
    Type of Medium: Electronic Resource
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