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Trans-cis amide bond isomerization in fulleroprolines (1998)

Bianco, Alberto ; Lucchini, Vittorio ; Maggini, Michele ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Journal of Peptide Science 4 (1998), S. 364-368

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Details

ISSN: 1075-2617

Keywords: trans-cis amide equilibrium ; dynamic nuclear magnetic resonance ; fulleroproline ; NOE differential spectroscopy ; proline ; Chemistry ; Biochemistry and Biotechnology

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The 1H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-l-Pro-OtBu over a range of temperatures in toluene-d8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond. © 1998 European Peptide Society and John Wiley & Sons, Ltd.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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