Bibliothek

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
  • 1
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 2617-2628 
    ISSN: 0887-6266
    Schlagwort(e): dibenzylidene sorbitol ; polymer crystal nucleation ; polypropylene ; clarifying agent ; Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Recent studies have demonstrated that addition of a small quantity of dibenzylidene sorbitol (DBS) to a molten polymer may result in a physical gel if conditions permit the DBS molecules to self-organize into a three-dimensional network composed of highly connected nanofibrils. If the polymer crystallizes, DBS may also serve as a nucleating agent, promoting the formation of spherulites, especially in commercially important polyolefins such as polypropylene. We examine the thermal and mechanical properties, as well as the morphological characteristics, of an isotactic polypropylene copolymer with 3 wt % ethylene upon addition of less than 1 wt % of 1,3:2,4-di-p-methylbenzylidene sorbitol (MDBS). From dynamic rheological measurements, pronounced complex viscosity increases, attributed to MDBS nanofibril network formation, are observed at concentration-dependent temperatures above the melting point of the nucleated copolymer. Transmission electron micrographs of RuO4-stained sections confirm the existence of MDBS nanofibrils measuring on the order of 10 nm in diameter and, at higher concentrations, fibrillar bundles measuring up to about 200 nm across and several microns in length. The addition of MDBS at different concentrations is also found to promote increases in optical clarity, yield strength, tensile strength, and ultimate elongation of modified copolymer formulations. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2617-2628, 1997
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 22 (1984), S. 1623-1634 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The tear behavior of unvulcanized natural rubber has been studied by using established techniques normally adopted for the study of vulcanized rubbers. Unvulcanized rubber has been found to tear in a relatively steady manner, in contrast to the stick-slip tear behavior of the vulcanized rubber, the tearing energy being dependent on the rate of tearing. Crystallization seems to be an important factor in determining the tear behavior since it has not been found possible to tear unvulcanized SBR under the same conditions. The effect of the pronounced imperfect elastic nature of the material was studied under conditions where the driving force for tearing was solely governed by the rate of release of elastic energy. Under such conditions, it has been found that the tearing energy is determined not by the strain energy required to stretch the material but by the energy which can be recovered on retraction. The set developed in the test piece, due to imperfect elasticity, has also to be taken into account.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 511-521 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: When certain substances, notably waxes, are incorporated into rubber during vulcanization, the surface of the vulcanized rubber may subsequently become covered by a film of the substance diffusing out. This phenomenon, known as blooming, depends on the substance being soluble at the vulcanization temperature but only partially soluble at the temperature of blooming. A study has been made using pure waxes in natural rubber vulcanizates with a range of crosslink densities. The mass of bloomed material has been determined as a function of time, and the expected dependence on the square root of the time has been found to hold over the anticipated range. It has been shown that the kinetics of the process cannot be explained simply in terms of the degree of supersaturation of the wax in the rubber, the observed rates being much too low. This appears to be related to the precipitation of the wax in the body of the material. A theory has been developed based on a calculation of the stresses set up around such a precipitated particle and the effect of the consequent free-energy gradient on the rate of diffusion. Comparison with experiment shows satisfactory agreement with the theory.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 21 (1983), S. 1807-1814 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: In a previous paper a two-network model for an elastomer in which crosslinks have been introduced in the strained state, similar to that proposed by Green and Tobolsky, was used to calculate the dependence of the incipient characteristic tearing energy on the number of chain segments in each of the two networks, the number of links in these chain segments, and the deformation at which the crosslinking takes place. The tearing energies were calculated for tearing on planes perpendicular to the principal directions of this deformation. Here the calculations are extended to cover tearing on a plane with arbitrary orientation.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    Developmental Genetics 4 (1983), S. 199-210 
    ISSN: 0192-253X
    Schlagwort(e): aging ; Drosophila ; behavior ; Life and Medical Sciences ; Genetics
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie
    Notizen: The question as to the role that genes play in determining life-span is essentially unresolved. Although it is well documented that genotype influences longevity, this is no way demonstrates that life-span is genetically determined. In the present study we examine five temperature-sensitive mutations for their effect on the aging process. At the permissive temperature (22°C ), the longevity of each mutant strain is comparable to that of wild type. However, at the restrictive temperature (29°C ) the life-span of these mutants is severely curtailed. Using behavior loss as a landmark of adult physiological age, we examined each of these strains for its pattern of behavior loss relative to longevity, and compared each to a wild-type strain. In four of the mutations the pattern of behavior loss relative to longevity was severely altered at one or both temperatures. However, one strain, adl-16tsl displayed a pattern of behavior loss that was indistinguishable from wild type at both 22°C and 29°C. At 29°C not only was the longevity decreased, the pattern of behavior loss was also compressed into a shorter time period. The compression of the pattern of behavior loss was proportional to the reduction in life-span. Thus it appears that this mutation, adl-16tsl, may accelerate the normal aging process when placed at 29°C. The potential utility of these types of mutants for studying the aging process is discussed.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 6
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    Developmental Genetics 4 (1983), S. 77-97 
    ISSN: 0192-253X
    Schlagwort(e): behavioral mutation ; Drosophila ; flightlessness ; temperature sensitive ; Life and Medical Sciences ; Genetics
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie
    Notizen: Mutations in 13 genes with temperature-sensitive (ts), flightless phenotypes have been examined. All hop and fly well when raised at the permissive temperature, but fly poorly, or not at all, when raised at the restrictive temperature. The mutations were divided into three groups on the basis of their temperature-sensitive periods (TSPs) for flightlessness. The TSPs for mutations at five loci, fli-C1, D1, E1, I1, and shak A1, in the first group are confined to 24 to 48 hr interval during early pupal development. Mutations in the second group, including eag101, fli B1, and futs1 have continuous TSPs 3 to 4 days in length, extending from late larval through the early pupal stages. The flight TSPs for mutations in the third class, including fli J1, fli K2, flrd H3, and flrd N1, are almost continuous, and span most of the larval and pupal periods. Many of the mutations have pleiotropic phenotypes, including semilethality and lethality, and wing posture and cuticle abnormalities, with discernible TSPs. One of the more intriguing pleiotropic phenotypes is the ts optomotor response exhibited by fli J2, the TSP for which extends from late larval through late pupal stages.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...