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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 6 (1983), S. 427-430 
    ISSN: 0935-6304
    Keywords: Capillary GC ; Electron capture detector ; Cell design ; Time constant, purge flow ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A comparison of the effects on peak shape is made between a 350 and 100 microliter displaced coaxial and a 350 microliter concentric cylinder electron capture cell. Peaks as fast as W1/2 = 0.5 second were detected using electronics operating in the constant current mode. The measured peak shapes are compared to those obtained by computer simulation assuming either complete mixing or plug-like flow within ECD cell. The advantage of controlling the flow pattern through the cell to obtain plug-like flow is demonstrated. Differences in peak shape between the displaced coaxial and concentric cylinder cells of the same volume are explained in terms of the electrostatic fields within the cells.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion fatigue behaviour of the to high ductility aged precipitation hardened steel PH 13-8 Mo and the X20 CrMoV 121 steam turbine blading steel in comparisonThe corrosion fatigue behaviour of the martensitic stainless steels PH 13-8 Mo and X20 CrMoV 121 is compared. The investigation includes both electrochemical and corrosion fatigue tests. Also mechanical, metallographical and SEM investigations were performed.The corrosion fatigue resistance at 150°C of the precipitation hardened steel PH 13-8 Mo in the modification with the higher strength level (cast I) varies between 100 and 135 MPa. The mean stress was 250 MPa. The influence of the pH-value is predominant to the Cl- -concentration. The corrosion fatigue resistance of the lower strength modification of PH 13-8 Mo (cast II) is significant lower than that of cast 1.At the conventional 12% Cr-steel cracks are initiated from notches caused by corrosion under salt like deposits primarily at the grain boundaries, weakened by carbide precipitations. At the PH 13-8 Mo steel the crack initiation is located at zones of plastic deformation between the martensitic laths. Corrosion attack occurred preferably by orthogonal orientation of the laths to the surface.
    Notes: Im folgenden wird das Schwingungsrißkorrosionsverhalten der Stähle PH 13-8 Mo und X20 CrMoV 121 verglichen. Die Untersuchungen hierzu umfaßten elektrochemische und Schwingungsrißkorrosions-Tests. Weiterhin wurden mechanische, metallographische und rasterelektronenmikroskopische Untersuchungen durchgeführt. Die Korrosionsschwingfestigkeit des auf höhere Festigkeit vergüteten Stahls PH 13-8 Mo (Charge I) variiert bei 150°C sowie 250 MPa Mittelspannung zwischen 100 und 135 MPa. Der pH-Wert beeinflußt den ertragenen Spannungsausschlag stärker als die Chloridkonzentration. Die auf die niedrigere Festigkeit vergütete zweite Charge erreicht eine deutlich geringere Korrosionsschwingfestigkeit.Die Risse gehen bei den 12% Cr-Stählen von Korrosionskerben aus, die durch den verstärkten Angriff der Korngrenzen unter salzartigen Belägen entstehen. Bei den martensitaushärtenden Stählen entstehen rilßauslösende Kerben durch den selektiven Angriff der plastisch verformten Zonen zwischen den Martensitnadeln, wobei bevorzugt Körner mit senkrecht zur Oberfläche orientierten Nadeln korrodieren.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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