ISSN:
0268-2605
Schlagwort(e):
surfactants
;
carbohydrate
;
carbosilane
;
silane
;
wetting
;
surface tension
;
Chemistry
;
Industrial Chemistry and Chemical Engineering
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The synthesis of carbohydrate surfactants bearing carbosilane, silane, polysilane and non-permethylated siloxane moieties is described. These surfactants consist of three structural elements: (1) a silicon-containing moiety, (2) a spacer and (3) a carbohydrate unit. Additionally two different types of mixed structures have been synthesized: (a) single-chained carbosilane-siloxane surfactants and (b) double-chained combinations of carbo- silanes, silanes and siloxanes. The wetting behaviour of the key intermediates, the allyl glycidyl derivatives, has been investigated by static surface tension (γlv, σ) and wetting tension (γsv-γsl, α) measurements on a non-polar perfluorinated surface (FEP® plate). The contact angles obtained for these pure liquids are not a linear function of the surface tension but depend on the polarity of the substructures. © 1998 John Wiley & Sons, Ltd.
Zusätzliches Material:
10 Ill.
Materialart:
Digitale Medien
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