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  • 1995-1999  (2)
  • 1975-1979
  • 1850-1859
  • surface tension  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Silicon-modified carbohydrate surfactants VI: Synthesis of carbosilane, silane, polysilane and non-permethylated siloxane derivatives; the wetting behaviour of epoxy-modified precursor liquids on non-polar surfacesIn remembrance of Professor Dr Edwin Hengge (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 47-58 
    Details
    ISSN: 0268-2605
    Keywords: surfactants ; carbohydrate ; carbosilane ; silane ; wetting ; surface tension ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of carbohydrate surfactants bearing carbosilane, silane, polysilane and non-permethylated siloxane moieties is described. These surfactants consist of three structural elements: (1) a silicon-containing moiety, (2) a spacer and (3) a carbohydrate unit. Additionally two different types of mixed structures have been synthesized: (a) single-chained carbosilane-siloxane surfactants and (b) double-chained combinations of carbo- silanes, silanes and siloxanes. The wetting behaviour of the key intermediates, the allyl glycidyl derivatives, has been investigated by static surface tension (γlv, σ) and wetting tension (γsv-γsl, α) measurements on a non-polar perfluorinated surface (FEP® plate). The contact angles obtained for these pure liquids are not a linear function of the surface tension but depend on the polarity of the substructures. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
  • 2
    Electronic Resource
    Electronic Resource
    Silicon-Modified Carbohydrate Surfactants V: The Wetting Behaviour of Low-Molecular-Weight Siloxane, Carbosilane, Silane and Polysilane Precursors on Low-Energy Surfaces (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 11 (1997), S. 645-657 
    Details
    ISSN: 0268-2605
    Keywords: siloxane ; surface tension ; control angle ; interfacial tension ; wetting tension ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The surface tensions, wetting tensions, contact angles and solid/liquid interfacial tensions of defined siloxanes as well as those of analogous carbosilanes, polysilanes and neopentyl substituted silanes were determined. The wetting experiments were carried out on a glass plate coated with perfluoroalkyl methacrylate (FC 722®). The siloxanes possess the lowest surface tensions. Due to the presence of oxygen atoms in the siloxane backbone, a donor-acceptor portion (γ+/-lv) of the surface tension of about 1-2 mN/m was determined. The solid/liquid interfacial tension also contains a donor-acceptor portion (γ+/-sl). Its value is almost identical to that of γ+/-lv. The γ+/-sl differences between individual molecules of the same surface tension are responsible for contact angle differences of up to 4°. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
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