ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On Reactions of Subgroup. VI. Hexacarbonyls with Tin(II) and Germanium (II) HalidesThe neutral complexes M(CO)5SnX2 and M(CO)5GeCl2 (M = Cr, Mo, W; X = Cl, Br, J) have been prepared by a photochemical reaction between M(CO)6 and SnX2, or CsGeCl3 in THF. The reaction of these compounds with [N(CH3)4]X (X = Cl, Br, J) in THF was found to lead to a series of anions [M(CO)5SnX3]- or [M(CO)5GeCl3]- (M = Cr, Mo, W; X = Cl, Br, J), some of which have previously been prepared. The physical properties and IR-spectra of the above compounds are discussed.
Notes:
Bei den photochemischen Umsetzungen von M(CO)6 (M = Cr, Mo, W) mit SnX2 (X = Cl, Br, J) bzw. CsGeCl3 in THF bilden sich die Neutralkomplexe M(CO)5SnX2 (M = Cr, Mo, W; X = Cl, Br, J) bzw. M(CO)5GeCl2 (M = Cr, Mo, W), deren Reaktionen mit [N(CH3)4]X (X = Cl, Br, J) in THF zu den zum Teil schon bekannten Anionen [M(CO)5SnX3]- (M = Cr, Mo, W; X = Cl, Br, J) bzw. [M(CO)5GeCl3]- (M = Cr, Mo, W) führen. Die Eigenschaften und IR-Spektren der genannten Verbindungen werden diskutiert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19734010304
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