ISSN:
0044-2313
Keywords:
Nickel(0) complexes
;
diphenylphosphanoalkane
;
1-diphenylphosphano-2-(2-pyridino)ethane
;
N-arylsulfinylamine ligands
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Bis(diphenylphosphano)alkane- and 1-Diphenylphosphano-2-(2-pyridino)ethane-N-arylsulfinylamine Nickel(0) ComplexesSynthesis and properties of the bis(diphenylphosphano)alkane-N-phenyl-sulfinylamine-nickel(0) complexes [Ni{Ph2P(CH2)nPPh2}(PhNSO)] (n = 2 dppe, n = 3 dppp, n = 4 dppb) as well as of the 1-(diphenylphosphano)-2-(2-pyridino)ethane nickel(0) complexes [Ni(dpppe)2], [Ni(dpppe)(p-TolNSO)] and [Ni(dpppe)(PPh3)2] are described.These compounds have been characterized by i. r. and 31P n.m.r. spectroscopy. The N-arylsulfinylamine ligands are η2-(N, S)-side on coordinated.
Notes:
Synthese und Eigenschaften der Bis(diphenylphosphano)alkan-N-Phenylsulfinylamin-Nickel(0)-Komplexe [Ni{Ph2P(CH2)nPPh2}(PhNSO)] (n = 2 dppe, n = 3 dppp, n = 4 dppb) sowie der 1-Diphenylphosphano-2-(2-pyridino)ethan-Nickel(0)-Komplexe [Ni(dpppe)2], [Ni(dpppe)(p-TolNSO)] und [Ni(dpppe)(PPh3)2] werden beschrieben.Die Charakterisierung der genannten Verbindungen erfolgte mit Hilfe der IR- und 31P-NMR-Spektroskopie. Die N-Arylsulfinylamin-Liganden sind η2-(N, S)-side on koordiniert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19956210317
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