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  • 1
    ISSN: 1434-601X
    Keywords: 21.10.−k ; 23.40.Hc ; 27.60,+j
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The EC/β+-decay of the odd-odd nucleus100Ag was studied by means of total absorptionγ-ray spectrometry. Most of the Gamow-Teller strength was found to be concentrated at an excitation energy of 5.6 MeV in100Pd, the FWHM of this resonance being 1.5 MeV. The measured strength distribution which is interpreted within the BCS approximation as being due to the dominant population of four-quasiparticle excitations, resembles the distribution predicted by an advanced shell-model calculation for the98Ag →98Cd decay.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 663-669 
    ISSN: 0044-2313
    Keywords: Dicopper(I)-octa-μ3-halogeno-hexahalogeno-octahedro-hexamolybdate(II) ; crystal structure ; Mo6X14-group ; trigonal planar CuX3-group ; ionic conduction ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Trigonal Planar CuX3-Groups in Cu2Mo6X14, X = Cl, Br, ICu2Mo6Cl14 (I), Cu2Mo6Br14 (II) and Cu2Mo6I14 (III) were synthesized by thermal treatment of corresponding mixtures of copper(I) and molybdenum(II) halides. The crystal structures were determined by single crystal X-ray analyses. I and II show isotypism, cubic, Pn3 (no. 201, sec. setting), Z = 4, I: a = 12.772(3) Å, II: a = 13.350(2) Å. III shows a new structural type, orthorhombic, Pbca (No. 61), Z = 4, a = 16.058(3) Å, b = 10.643(2) Å, c = 16.963(3) Å. Trigonal planar CuX3 units were found in I—III. Structural behaviour relations are discussed, especially with regard to ionic conductivity.
    Notes: Cu2Mo6Cl14 (I), Cu2Mo6Br14 (II) und Cu2Mo6I14 (III) wurden durch thermische Behandlung der Gemenge der binären Halogenide CuX und Mo6X12 im molaren Verhältnis 2:1 in einkristalliner Form erhalten. Röntgenographische Strukturbestimmung wurde an Einkristallen durchgeführt. I und II zeigen Isotypie, Pn3 (Nr. 201, sec. setting) Z = 4, I: a = 12,772(3) Å, II: a = 13,350(2) Å. III weist eigenen Strukturtyp auf: Pbca (Nr. 61), Z = 4, a = 16,058(3) Å, b = 10,643(2) Å, c = 16,963(3) Å. In I—III liegen trigonal planare CuX3-Gruppen vor. Bindungsverhältnisse und Meßergebnisse der Ionenleitfähigkeit werden diskutiert.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 1231-1235 
    ISSN: 0044-2313
    Keywords: Dilead(II)-hexahalogenopalladate(II) ; crystal structure ; strongly elongated PdX6 octahedra ; DTA, IR/RAMAN, 207Pb MAS NMR ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Pb2PdX6 (X = Cl, Br) - Compounds with Elongated [PdX6] OctahedraIn contradiction to published data new compounds in the systems PbX2 - PdX2 (X = Cl, Br) with the formula Pb2PdCl6 (I) and Pb2PdBr6 (II) were found. These were synthesized by thermal treatment of the corresponding mixtures of PbX2 and PdX2 (X = Cl, Br). X-ray single crystal structure analysis shows isotypism of I and II, monoclinic, P21/c (No. 14), Z = 2, I: a = 9.037(2) Å, b = 6.224(1) Å, c = 8.162(1) Å, β = 90.31(7)β, II: a = 9.512(7) Å, b = 6.584(8) Å, c = 8.383(3) Å, β = 90.07(5)º. Strongly elongated PdX6 octahedra are found in the crystal structure. Additional characterisation of the compounds was done by DTA, IR/RAMAN spectra and 207Pb MAS NMR investigations. Remarcable low field shifts were found for 207Pb.
    Notes: Entgegen Literaturangaben wurden in den Systemen PbX2 - PdX2 (X = Cl, Br) die neuen Verbindungen Pb2PdCl6(I) und Pb2PdBr6(II) aufgefunden. Sie wurden durch thermische Behandlung der binären Halogenide PbX2 und PdX2 im molaren Verhältnis 2:1 dargestellt (Einkristalle). Die Kristallstrukturen wurden mit Einkristallröntgenuntersuchungen ermittelt. I und II sind isotyp, monoklin, P21/c (Nr. 14), Z = 2, I: a = 9,037(2) Å, b = 6,224(1) Å, c = 8,162(1) Å, β = 90,31(7)º, II: a = 9,512(7) Å, b = 6,584(8) Å, c = 8,383(3) Å, β = 90,07(5)º. In Pb2PdX6 werden stark gestreckte PdX6-Oktaeder beobachtet. Die Verbindungen wurden außerdem mittels DTA, IR/RAMAN-Spektren und 207Pb-MAS-NMR-Untersuchungen charakterisiert. Für 207Pb wurde eine bemerkenswerte Tieffeldverschiebung beobachtet.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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