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  • 1995-1999  (3)
  • (CH3)4N+CF3IONO2-  (1)
  • 19F NMR  (1)
  • 19F13C NMR  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Darstellung von Trifluormethylhalogen-Iodaten(I) des Typs (CH3)4N+CF3IX- (X = F, Cl, Br) und Trifluormethyltrifluormethoxyiodat(I) (CH3)4N+CF3IOCF3- (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 1749-1755 
    Details
    ISSN: 0044-2313
    Keywords: Tetramethylammonium trifluormethoxytrifluormethyliodate(I) ; Tetramethylammonium fluorotrifluormethyliodate(I) ; Tetramethylammonium chlorotrifluormethyliodate(I) ; Tetramethylammonium bromotrifluormethyliodate(I) ; vibrational spectra ; 19F13C NMR ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of Trifluormethylhalogen Iodate(I) Salts (CH3)4N+CF3IX- (X = F, Cl, Br) and Trifluormethyltrifluormethoxy Iodate(I) (CH3)4N+CF3IOCF3-We describe the preparation of new trifluormethyliodate(I) salts CF3IX- (X = F, Cl, Br, OCF3). (CH3)4N+CF3ICl- and (CH3)4N+CF3IBr- are obtained via addition of CF3I with the corresponded tetramethylammonium halogenide. (CH3)4N+CF3IOCF3- is synthesized by comproportionation of (CH3)4N+CF3ICl- with CF3OCl under formation of Cl2 at -78°C. (CH3)4N+CF3IF- is formed either, through thermolysis of (CH3)4N+ CF3IOCF3- under separation of COF2, or reaction of CF3I with (CH3)4N+ OCF3-. The thermolabile compounds have been characterized by i.r., Raman, 19F-, 13C NMR spectroscopy.
    Notes: Es wird über die Darstellung einer Reihe neuer Iodate(I) des Typs CF3IX- (X = F, Cl, Br, OCF3) berichtet. (CH3)4N+CF3ICl- und (CH3)4N+CF3IBr- werden durch Additionsreaktion von CF3I an die entsprechenden Tetramethylammoniumhalogenide dargestellt. (CH3)4N+CF3IOCF3- erhält man durch Komproportionierung von (CH3)4N+CF3ICl- mit CF3OCl bei -78°C. CF3IF- entsteht sowohl, durch die Thermolyse von (CH3)4N+ CF3IOCF3- unter Abspaltung von COF2 bei -20°C, als auch durch Umsetzung von CF3I mit (CH3)4N+OCF3- bei -20°C.Die thermolabilen Verbindungen werden durch IR-, Raman-sowie Multikern-NMR-Spektroskopie charakterisiert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19966221020
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  • 2
    Electronic Resource
    Electronic Resource
    Neue N,N-Dichlormethylsulfonammoniumsalze CH3S(O)2NCl2X+MF6- (X = CH3, Cl, F; M = As, Sb) und Kristallstruktur von CH3S(O)2NCl2 (1997)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 333-339 
    Details
    ISSN: 0044-2313
    Keywords: N,N-Dichloromethylsulfonammonium salts ; crystal structure of CH3S(O)2NCl2 ; vibrational spectra ; 1H ; 13C ; 19F NMR ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New N,N-Dichloromethylsulfonammonium Salts CH3S(O)2NCl2X+MF6- (X = CH3, Cl, F; M = As, Sb) and Crystal Structure of CH3S(O)2NCl2The preparations of new dichlorammonium salts CH3S(O)2NCl2X+MF6- (X = CH3, Cl, F; M = As, Sb) and of CH3S(O)2NCl2 by oxidative halogenation respectively methylation are reported. The thermolabil compounds are characterized by IR, Raman, 1H, 13C, 19F NMR spectroscopy. N,N-Dichlormethylsulfonamid CH3S(O)2NCl2 crystallizes at 173(1) K in the orthorhombic space group Pnma with a = 615.1(3) pm, b = 937.3(5) pm, c = 970.3(5) pm and Z = 4.
    Notes: Die Darstellung einer Reihe von Dichlor ammoniumsalzen des Typs CH3S(O)2NCl2X+MF6- (X = CH3, Cl, F; M = As, Sb) wird angegeben. Die Salze werden durch oxidative Halogenierung bzw. Methylierung von CH3S(O)2NCl2 erhalten. Die Charakterisierung der thermolabilen Verbindungen erfolgte mittels IR-, Raman-sowie Multikern-NMR-Spektroskopie. Die Einkristallröntgenstrukturanalyse von N,N-Dichlormethylsulfonamid CH3S(O)2NCl2 bei 173(1) K ergab: orthorhombische Raum gruppe Pnma mit a = 615,1(3) pm, b = 937,3(5) pm, c = 970,3(5) pm und Z = 4.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19976230153
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  • 3
    Electronic Resource
    Electronic Resource
    Darstellung und spektroskopische Charakterisierung von Tetramethylammoniumtrifluormethylnitratoiodat(I) (CH3)4N+CF3IONO2-Professor Peter Satori zum 65. Geburtstag gewidmet (1997)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 151-154 
    Details
    ISSN: 0044-2313
    Keywords: Chlorine Nitrate ; Tetramethylammoniumtrifluoromethylnitratoiodate(I) ; (CH3)4N+CF3IONO2- ; vibrational spectra ; Halogen Nitrates ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Formation and Spectroscopic Characterization of Tetramethylammoniumtrifluoromethylnitratoiodate(I) (CH3)4N+CF3IONO2-(CH3)4N+CF3ICI- reacts with CIONO2 to (CH3)4N +CF3IONO2-. The salt is characterized by vibrational spectra.
    Notes: (CH3)4N+CF3ICI- reagiert mit ClONO2 unter Chlorkomproportionierung zu (CH3)4N+CF3IONO2-. Das erhaltene Salz wird schwingungsspektroskopisch charakterisiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19976230125
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    Paper (German National Licenses)
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