ISSN:
1572-8927
Keywords:
Solvent isotope effects
;
methanols
;
H/D-isotopomers
;
aqueous solutions
;
volumetric properties
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Densities of H/D-isotopomers mixtures of water (H2O, D2O) and methanol (CH3OH, CD3OH, CH3OD, and CD3OD) over the full range of compositions were measured at 5, 15, 25, 35, and 45°C. Results have been used to calculate molar volumes, excess molar volumes, apparent molar volumes, and isotope effects of the mixtures. The volumetric properties are discussed in terms of the structural changes in water-methanol solutions under the influence of isotope substitution.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00972689
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