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  • 1995-1999  (2)
  • 76.30.P  (1)
  • Capillary electrophoresis  (1)
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  • 1995-1999  (2)
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  • 1
    ISSN: 1434-6036
    Keywords: 75.20 ; 72.90 ; 61.65 ; 76.30.P
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Crystal structure, microwave conductivity and static magnetic susceptibility were analyzed for the conducting perylene (PE) radical cation salts of nominal composition (PE)2(PF6)1−x (AsF6) x ·2/3 THF for 0≦x≦1. Crystallographic phase transitions in the high-temperature metal phase were also characterized by differential scanning calorimetry and electron spin resonance. The Peierls transition occuring at 100–120 K (depending onx) and the opening of the energy gap in the semiconductor phase were determined from the magnetic data. The dependence of these properties on the size of the complex anions and the packing of the PE molecules is discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electroanalysis 8 (1996), S. 722-725 
    ISSN: 1040-0397
    Keywords: Conductometry ; Detection ; Capillary electrophoresis ; Capillary HPLC ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A simple electrochemical cell has been constructed for conductometric detection in capillary electrophoresis or HPLC. A platinum ring electrode is chemically deposited at the capillary end and the other electrode, a platinum wire, is immersed, together with the capillary, in a vessel containing the running buffer or the mobile phase used. The cell has been tested on a model system and its operational parameters have been discussed. The measurement is very sensitive (a limit of determination of ca. 3 × 10-9 M for potassium ions) and the detector response is rapid, comparable with that of the UV photometric detector. The dynamic range is wide (at least five concentration decades) but is nonlinear at high concentrations.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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