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  • 1995-1999  (2)
  • Al2O3 SCALES  (1)
  • Neural transplantation
  • Polymer and Materials Science
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 49 (1998), S. 187-212 
    ISSN: 1573-4889
    Keywords: Al2O3 SCALES ; GROWTH STRESS ; LATERAL GROWTH ; STRESS RELAXATION ; HIGH-TEMPERATURE OXIDATION
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The residual biaxial stress inAl2O3 scales formed duringoxidation of Fe-22.0%Cr-4.8%Al-0.3%Y in the temperaturerange 1000-1300°C have been measured usingCr3+ luminescence piezospectroscopy. Thestress measurements together with substantialdimensional changes of the specimens show that oxidationproduces high compressive growth stresses in theAl2O3 scale in addition tothermal-mismatch stresses that arise during cooling from the oxidationtemperature. The magnitude of the growth stress isdetermined by two opposing processes: stress generation,associated with lateral growth of the scale, and stress relaxation in both the metal and oxide. Thescale lateralgrowth strain continuously increasesconcurrently with the scale thickening. Creep in theoxide is a major relaxation process when the scale isthin, while metal deformation becomes significantduring the later stages of oxidation at highertemperatures.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 32 (1996), S. 119-124 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Crystallization kinetics studies for six experimental glass formulations in the system Na2O-CaO-SiO2-P2O5 synthesized by wet chemistry were conducted by means of differential thermal analysis. These glasses had CaO/P2O5 and SiO2/(CaO + Na2O) ratios ranging from 8.74-3.38 and 0.92-3.03, respectively. Samples of each glass (n = 30 were heated from 23 to 1250°C under N2 atmosphere at heating rates ranging from 10 to 50°C/min. Glass-ceramics were obtained after heat treating the initial glasses at temperatures determined from their DTA exotherms. The activation energy of crystallization for each glass composition was calculated from an expression-relating log-heating rate and the reciprocal of the exothermic peak temperature. The compositions of the six glasses were significantly different (p = 0.05). The activation energy of crystallization (Q) values ranged from 196 to 782 kJ/mole. A correlation was obtained between Q and CaO/P2O5 and between Q and the Young's modulus (p 〈 0.001). Two of the six glasses exhibited bulk crystallization. X-ray diffraction studies showed that four of the six glasses exhibited different proportions of crystalline phases following heat treatment. These phases were wollastonite (CaSiO3), Na2CaSi3O9, combeite [Na4Ca3SI6O16(OH)2], and some unidentifiable phases. Two of the six bioceramic materials had a mixture of unknown crystalline phases. © 1996 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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