ISSN:
1435-1528
Schlagwort(e):
Key words Monodomain
;
Conoscopy
;
Alignment angle
;
Shear
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
Abstract Orientational changes in monodomains of flow-aligning liquid crystals, 4-n-pentyl-4′-cyanobiphenyl and N-(4-methoxybenzylidene)-4-butylaniline, were studied during shear and recovery in a linear shearing device fitted to an optical microscope. Planar alignment (director in the shear plane) allows the study of twist effects and was generated by strong planar anchoring at the walls with orientations in a range of 0–90° with the shear direction. While being held back by the anchoring walls, shear caused the bulk director to rotate towards a steady-state alignment angle in the shear direction (Leslie angle θL). The transient director rotation was observed with conoscopy. It was found that increasing the initial alignment towards the vorticity direction increased the measured θL. Upon stopping the flow, the bulk director returned to its initial state. With initial alignment orientation changing from parallel to perpendicular to the flow direction, the rate of the twist-driven recovery process increases. This rate increase is not seen in the splay-driven recovery which is constant and consistently faster than twist-driven recovery at all orientations studied.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/s003970050203
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