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  • 1995-1999  (3)
  • Physical Chemistry  (2)
  • Calcium  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Combined effects of nitrogen and elevated CO2 on soils from controlled environment studies (1995)
    Springer
    Water, air & soil pollution 85 (1995), S. 1551-1556 
    Details
    ISSN: 1573-2932
    Keywords: Nitrogen ; Carbon dioxide ; Phosphorus ; Calcium ; Potassium ; Magnesium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper describes the effects of elevated CO2 and N fertilization on soils planted with ponderosa pine (Pinus ponderosa) seedlings in short-term greenhouse studies. The high degree of homogeneity in the soils used allowed sensitive evaluation of soil changes in response to treatments. Elevated CO2 had no detectable effect upon soil N availability, but both CO2 and N fertilization caused significant changes in soil available (NH4F/HCl-extractable) P. Some of these changes could be accounted for by plant uptake, some were apparently due to differences in P immobilization (biotic or abiotic). N fertilization caused reductions in exchangeable K, Ca and Mg which could not be accounted for by plant uptake and were probably due to increased leaching. None of the reductions in soil available nutrients observed were of sufficient magnitude to cause nutrient deficiencies over the approximate 1-year duration of these studies.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00477201
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  • 2
    Electronic Resource
    Electronic Resource
    A diode laser study of the Cl + CH3CO reaction (1997)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 29 (1997), S. 421-429 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Real-time kinetic measurements are reported for the Cl + CH3CO → CH2CO + HCl reaction. The experiments utilize infrared spectroscopy to determine the time dependence of the ketene formed via this reaction and of the CO produced from the subsequent rapid reaction between chlorine atoms and ketene. The reaction is investigated over a pressure range of 10-200 torr and a temperature range of 215-353 K. Within experimental error the rate constant under these conditions is k5a = (1.8 ± 0.5) × 10-10 cm3 s-1. We have also examined the Cl + CH2CO reaction and found it to have a rate constant of k6 = (2.5 ± 0.5) × 10-10 cm3 s-1 independent of temperature. © John Wiley & Sons, Inc. Int J Chem Kinet 29: 421-429, 1997.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 3
    Electronic Resource
    Electronic Resource
    Kinetics and mechanism of the reaction of Cl atoms with CH2 CO (Ketene) (1996)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 28 (1996), S. 627-635 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics and mechanism of the gas-phase reaction of Cl atoms with CH2CO have been studied with a FTIR spectrometer/smog chamber apparatus. Using relative rate methods the rate of reaction of Cl atoms with ketene was found to be independent of total pressure over the range 1-700 torr of air diluent with a rate constant of (2.7 ± 0.5) × 10-10 cm3 molecule-1 s-1 at 295 K. The reaction proceeds via an addition mechanism to give a chloroacetyl radical (CH2ClCO) which has a high degree of internal excitation and undergoes rapid unimolecular decomposition to give a CH2Cl radical and CO. Chloroacetyl radicals were also produced by the reaction of Cl atoms with CH2ClCHO; no decomposition was observed in this case. The rates of addition reactions are usually pressure dependent with the rate increasing with pressure reflecting increased collisional stabilization of the adduct. The absence of such behavior in the reaction of Cl atoms with CH2CO combined with the fact that the reaction rate is close to the gas kinetic limit is attributed to preferential decomposition of excited CH2ClCO radicals to CH2Cl radicals and CO as products as opposed to decomposition to reform the reactants. As part of this work ab initio quantum mechanical calculations (MP2/6-31G(d,p)) were used to derive ΔfH298(CH2ClCO) = -(5.4 ± 4.0) kcal mol-1. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.8
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    Paper (German National Licenses)
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