Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 1995-1999  (3)
  • Chemistry  (2)
  • General Chemistry
  • PEM fuel cell
  • 1
    ISSN: 1572-8838
    Keywords: anode ; nanocrystalline ; PEFC ; PEM fuel cell ; Pt–Ru alloy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract High energy ball milling, an industrially amenable technique, has been used to produce CO tolerant unsupported Pt–Ru based catalysts for the oxidation of hydrogen in polymer electrolyte fuel cells. Nanocrystalline Pt0.5–Ru0.5 alloys are easily obtained by ball-milling but their performances as anode catalysts are poor because nanocrystals composing the material aggregate during milling into larger particles. The result is a low specific area material. Improved specific areas were obtained by milling together Pt, Ru and a metal leacheable after the milling step. The best results were obtained by milling Pt, Ru, and Al in a 1:1:8 atomic ratio. After leaching Al, this catalyst (Pt0.5–Ru0.5 (Al4)) displays a specific area of 38 m2g−1. Pt0.5–Ru0.5 (Al4) is a composite catalyst. It consists of two components: (i) small crystallites (∼4 nm) of a Pt–Al solid solution (1–3 Al wt%) of low Ru content, and (ii) larger Ru crystallites. It shows hydrogen oxidation performance and CO tolerance equivalent to those of Pt0.5–Ru0.5 Black from Johnson Matthey, the commercial catalyst which was found to be the most CO tolerant one in this study.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 28 (1997), S. 571-574 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Measurements effect of elastic waves in steel- and rock rods using the magneto-elasticStress waves in steel and iron ore rods produced by a mechanical impact can be measured by a sensor using the magneto-elastic effect. A detection of the changing magnetic flux is made. The function describing the propagation of longitudinal waves in rods is known as the stress wave equation. The agreement with theory is verified by examinations of steel rods using strain gauges. Afterwards the signals of three iron ores (magnetite, hematite, siderite) are recorded. Induced voltage is measured by the magneto-elastic sensor in the case of magnetite and hematite, however it is not possible to detect any signal for siderite. This means that the change of magnetic flux depends on the kind of bulk magnetic appearance, not on content of iron.Using the magneto-elastic sensor the magneto-elastic effect offers the possibility to detect tree of contact mechanical waves produced by a mechanical impact in ferro- or ferrimagnetic solids.
    Notes: An Stahl- und Eisenerzstäben werden die durch einen Stoß ausgelösten elastischen Dehnwellen mit Hilfe eines Sensors gemessen, der den magnetoelastischen Effekt ausnutzt. Detektiert wird dabei die Änderung des magnetischern Flusses. Die theoretische Beschreibung der Ausbreitung elastischer Längswellen in Stäben erfolgt mit Hilfe der eindimensionalen Dehnwellengleichung. Die Übereinstimmung mit der Theorie wird exemplarisch durch Untersuchungen an Stahlstäben mittels Dehnungsmeßstreifen verifiziert. Danach werden die Signale von drei Eisenerzstäben (Magnetit, Hämatit, Siderit) aufgenommen. Bei den Gesteinen Magnetit und Hämatit lassen sich mit dem magnetoelastischen Aufnehmer Induktionsspannungen messen, während beim Siderit keine Signale aufgezeichnet werden konnten. Das bedeutet, daß für die Änderung des magnetischen Flusses nicht der Eisengehalt, sondern die Art der äußeren magnetischen Erscheinungsform der Proben entscheidend ist.Der magnetoelastische Effekt bietet somit die Möglichkeit die durch eine Stoßbelastung in ferro- bzw. ferrimagnetischen Materialien ausgelösten mechanischen Wellen berührungslos mit Hilfe eines magnetoelastischen Sensors zu erfassen.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 46 (1995), S. 130-133 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polystyrene-block-poly-1-azabicyclooctane[4,2,0] has been modified by protonation or alkylation of the polyamine moiety. Short chain alkyl iodides lead to quantitatively quarternized products while longer alkyl chains or alkyl-bromides give incomplete conversion. The viscosimetric behavior of the charged blockcopolymers is dominated by the polyelectrolyte block although the polyelectrolyte effect is drastically reduced by the presence of the polystyrene block.The blockcopolymers are insoluble in water, but concentrated solutions of the polymers in DMF can be diluted with any amount of water without any precipitation. Although the blockcopolymers have an amphiphilic structure they do not exhibit any surface activity. In a water/DMF (9/1) solution the polymers have a core-shell micelle-like structure of collapsed polystyrene block which is solubilized by the surrounding polyelectrolyte block.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...