ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Perrhenate-Catalyzed Rearrangement of Ethinyl-β-ionolThe rearrangement of 2-ethinyl-β-ionol (1) to α,β-unsaturated carbonyl compounds using tetraalkylammonium perrhenate catalysts was studied. It was found that the Rupe-Kambli product, ketone 2, is the main product (ca. 70%) of this rearrangement. The by-product 4 (ca. 15%) is formed in a ring-closure reaction.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19960790307
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