ISSN:
1572-9001
Keywords:
Conglomerate crystallization
;
trans-Co(III)amines
;
homochiral cations
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A racemic solution of (I) crystallizes as a conglomerate from which a crystal we selected was found to be (+)546-trans-[Co(3,2,3-tet)(NO2)2]Cl·3H2O (I), CoClO7N6C8H28. It crystallizes in the enantiomorphic space groupP2l2l2l, with lattice constantsa=18.501(15) å,b=14.433(2) å, andc=6.441(3) å;V=1720.07 å3 andd(calc. M.W.=414.73,Z=4)=1.601 g cm−3. A total of 2305 data were collected over the range of 4
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02281735
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