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  • 1995-1999  (2)
  • Electrocatalysis  (1)
  • Engineering  (1)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Mechanics of Cohesive-frictional Materials 3 (1998), S. 155-180 
    ISSN: 1082-5010
    Keywords: reinforced concrete ; bond model ; plasticity ; interface ; yield surface ; modelling ; Engineering ; Civil and Mechanical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The development of an interface, non-associative, plasticity model for bond between ribbed, steel bars and concrete is discussed. The model relates average local slip and radial dilation to average bond shear stress and radial confinement stress. The model partially accounts for the response of the damaged, finite-thickness region around the bar - the bond zone. The model is developed for standard steel bars that are initially unstrained. With simplifying assumptions, data for the components of a plasticity law are extracted from a key set of experimental results. In this paper, we emphasize the development of an expression for the yield surface for monotonic loading. While the forms of the model's components are empirically derived, they qualitatively reflect the mechanics of the mechanical interaction of ribbed bars with the adjacent concrete. A characteristic length, related to the rib pattern, helps quantify this interaction. The mechanics of the bond are difficult to characterize in a simple form, but the calibrated model only requires four physical properties and reproduces with acceptable accuracy experimental results with various levels of radial confinement stress. Model refinements are suggested for future work. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1040-0397
    Keywords: Heparin ; Modified electrodes ; Electrocatalysis ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrochemical oxidation of full-size heparin (13-15 kDa) is demonstrated in 1 M H3PO4 at a glassy carbon electrode coated with a ruthenium oxide film. The pathway apparently is analogous to chemical oxidation by periodate. By comparison to currents from inorganic species, it is apparent that only about 2 electrons per mole are involved. Flow injection analysis (FIA) allowed determinations down to 2 μM heparin, but the calibration plot was nonlinear. Low molecular weight heparin (5-6 kDa) was not electroactive with this system. In basic solution at a glassy carbon electrode that is modified with a film of Cu2O, both full-size and low molecular weight heparin are oxidized. The pathways involved oxidative desulfation and attack on saccharide units with evolution of CO2. Linear calibration plots which extended into the sub-μM level were obtained by FIA. The detection limits, which were based on a value of 3 for the ratio of the signal to the standard deviation of replicates, were 9 nM for full-size and 20-30 nM for various low molecular weight heparin samples.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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