ISSN:
1572-8943
Keywords:
cobalt
;
isomorphous substitution
;
manganese
;
tetraalkylammonium cations
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Pure silica zeolite ZSM-5 has been synthesised in a slightly acidic aqueous fluoride medium which produces the protonated form of the zeolite ZSM-5 [1]. Tetrahalometallate [2] species of cobalt and manganese have been synthesised and increasing mole fractions incorporated into the zeolite synthesis gel. The products have been analysed and characterised using simultaneous thermogravimetric-derivative thermogravimetric analysis (TG-DTG). The thermal decomposition, under nitrogen of the associated tetraethylammonium (TEA+) and tetrapropylammonium (TPA+) cations occluded within the zeolite channels is indicative and characteristic of the incorporation of the heteroatoms into the zeolitic framework. Analysis by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray fluorescence (XRF), and Fourier transform infrared spectroscopy (FTIR) has confirmed the reliability of thermogravimetric (TG) and derived thermogravimetric analysis (DTG) as a diagnostic tool.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010116625710
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