ISSN:
0009-2940
Keywords:
Gold
;
Phosphanes
;
Phosphaneimines
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
[Tris(dimethylamino)phosphane]gold(I) chloride, μ-tris-{[tris(dimethylamino)phosphane]gold(I)}oxonium tetrafluoroborate, {μ3-tris(dimethylamino)phosphaneimidotris[tris(dimethylamino)phosphane]gold(I)}(2+) bis(tetrafluoroborate) and N-trimethylsilyltris(dimethylamino)phosphaneimine were prepared using modifications of established procedures. Their structures were determined in single-crystal X-ray diffraction studies. The ligand (Me2N)3P, here introduced into gold(I) chemistry for the first time, lends high stability to these compounds through efficient steric shielding of the reaction sites and through a balanced electronic substituent effect. The structural details of the (Mr2N)3P groups are of current interest because of the unusual nonequivalent configuration of the nitrogen atoms in the dimethylamino groups. This behaviour has been observed for most of the (Me2N)3P units in the compounds studied in this work.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300304
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