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Steroids, LIII: New routes to aminosteroids (1996)

Szendi, Z. ; Dombi, G. ; Vincze, I.

Springer

Monatshefte für Chemie 127 (1996), S. 1189-1196

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ISSN: 1434-4475

Keywords: Steroids ; Aminosteroids ; Reduction of ketoximes ; NiCl2/NaBH4 and MoO3/NaBH4-reagents

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Zusammenfassung Oxime von Ketosteroiden wurden mit NaBH4 in Gegenwart von NiCl2 und MoO3 reduziert. Dieses Verfahren lieferte 17α- und 20α-Aminosteroide(1c–5c) in größeren Ausbeuten als übliche Methoden.

Notes: Summary Steroid ketoximes were reduced with sodium tetrahydroborate in the presence of nickel chloride or molybdenum trioxide. These processes yielded 17α- and 20α-aminosteroids (1c–5c) in higher yields than common reduction methods.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00844694

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