ISSN:
1573-4994
Keywords:
Ru(II) complexes
;
energy gap law
;
alcohols
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The excited state of Ru(II)[bpy]3 2+ dissolved in hydroxylic solvents is subject to specific solvent effects, which were hitherto not understood on a quantitative basis. We determined the solvent effects of linear monovalent alcohols on the energy gap law of internal conversion with the help of lifetime and intensity measurements. An on-line method for measurement of the temperature dependence of quantum efficiencies was introduced. A modified Franck-Condon analysis of emission spectra by taking into account the shape of a Morse potential of the involved states was applied to compute excited-state energies.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00727536
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