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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 47 (1996), S. 871-877 
    ISSN: 1572-8943
    Keywords: complexes ; zeolite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A new zeolite derivative has been prepared by interacting Th(IV) and complexone in HCl medium and neutralising with aqueous ammonia. The amorphous and siliceous derivative showed a total mass loss of 29.25% in TG for stepwise dehydration, dehydroxylation and decomposition. Heats of reaction were 1167.6 J g−1 at 88.7°C and 75.167 J g−1 at 492.5°C for loss of volatile components and decomposition respectively.29Si and27Al MAS NMR spectra as well as XRD data of the derivative before and after calcination indicate presence of both four-coordinated and six-coordinated Al in varying ratios and the total loss of crystallinity.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 93 (1998), S. 109-141 
    ISSN: 1572-9613
    Keywords: Thermodynamic limit ; ferrofluid ; polar fluid ; dipole ; magnetism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We prove existence of a shape- and boundary-condition-independent thermodynamic limit for fluids and solids of identical particles with electric or magnetic dipole moments. Our result applies to fluids of hard-core particles, to dipolar soft spheres and Stockmayer fluids, to disordered solid composites, and to regular crystal lattices. In addition to their permanent dipole moments, particles may further polarize each other. Classical and quantum models are treated. Shape independence depends on the reduction in free energy accomplished by domain formation, so our proof applies only in the case of zero applied field. Existence of a thermodynamic limit implies texture formation in spontaneously magnetized liquids and disordered solids analogous to domain formation in crystalline solids.
    Type of Medium: Electronic Resource
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