ISSN:
1573-1111
Keywords:
azocrown ether
;
lithium complex
;
X-ray structure
;
membrane electrodes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The lithium bromide hydrate complex ofthe 13-membered dibenzoazocrown ether of composition{[LiL13(H2O)]Br}2 has been synthesized. Its structure has been determined by the X-ray method. Thecrystals are monoclinic, space group C2/c, a =12.720(6), b = 19.969(9), c = 13.963(6)Å; β = 104.32(2)°. Selectivities of membraneelectrodes based on 13-membered azocrown ethers arediscussed in terms of complex stabilities and metalcation extractabilities as related to the structuresof the respective complexes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1007940713524
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