ISSN:
1573-4803
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Maschinenbau
Notizen:
Abstract In the highly alkaline environment of the cement paste of a concrete, a source of silica can potentially react in two ways. In the pozzolanic reaction, it can combine with free lime to generate additional calcium silicate hydrate binding phase. Alternatively, reaction with alkali to form a gel can occur; this gel may swell and degrade the concrete. 29Si magic angle spinning (MAS) and cross-polarization (CP) MAS nuclear magnetic resonance (NMR) studies have been performed to determine the silicate connectivity in some model cement systems; 29Si enrichment was utilized to enable a series of spectra to be acquired in situ from a single sample. The hydrate from pozzolanic reaction of lime with silica was similar to the hydrate formed around silica in blended pozzolanic cements, with a relatively high crystallinity and long silicate chains. In the absence of lime, silica reacted with an alkaline solution to produce a gel having a high degree of cross linking, and a range of silicate mobilities. Tricalcium silicate hydration was found to be accelerated significantly by high levels of alkali (KOH) in solution; the hydrate formed had shorter silicate chains and was more crystalline than that produced by reaction in pure water. Hydration in alkali solution of a model blended cement, comprising a mixture of tricalcium silicate and silica, gave rise to two products, a long chain calcium silicate hydrate (C-S-H) and an alkali silicate of low rigidity. The alkali silicate phase gradually polymerized; at later ages it underwent a phase change, although no crystalline phase appeared to be formed. Silicate exchange took place between the C-S-H and the alkali silicate phase at a slow rate.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00360736
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